ArticleJournal of the American Chemical Society2013
Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Regiodivergent Hydrosilylation of Alkenes at Nickel: Tuning the Selectivity by Complex Stoichiometry and Silane Identity.Inorganic chemistry · 2026Article
- The influential IPr: 25 years after its discovery.Chemical science · 2025Review
- One-Pot Synthesis of Styrene Derivatives from Allyl Silanes via B(COrganic letters · 2022Article
- Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes.Nature communications · 2022Article
- Case Study of N-Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Halonium Catalysis: An Underutilized and Underexplored Catalytic Concept in Olefin Functionalizations.Synlett : accounts and rapid communications in synthetic organic chemistry · 2021Article
- Biomimetic caged platinum catalyst for hydrosilylation reaction with high site selectivity.Nature communications · 2021Article
- Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes.Chemical science · 2018Article
- Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes.Nature communications · 2017Article
- NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings.Journal of the American Chemical Society · 2017Article
- Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes.Organic letters · 2016Article
- Mechanistic Basis for Regioselection and Regiodivergence in Nickel-Catalyzed Reductive Couplings.Accounts of chemical research · 2015Article
- Exo-selective reductive macrocyclization of ynals.Organic letters · 2015Article
- Regiocontrol in catalytic reductive couplings through alterations of silane rate dependence.Journal of the American Chemical Society · 2015Article
- Regioselective allene hydroarylation via one-pot allene hydrosilylation/Pd-catalyzed cross-coupling.Organic letters · 2014Article
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Authors and funding
4 authors.
Funding
Abstract
Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by the choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene (NHC) ligands, and allylsilanes are produced via palladium catalysis with smaller NHC ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol.
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