ArticleJournal of the American Chemical Society2013
Total synthesis of maoecrystal V: early-stage C-H functionalization and lactone assembly by radical cyclization.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Dearomative logic in natural product total synthesis.Natural product reports · 2022Review
- Ideality in Context: Motivations for Total Synthesis.Accounts of chemical research · 2021Article
- Dearomatization of Electron-Deficient Phenols to ortho-Quinones: Bidentate Nitrogen-Ligated Iodine(V) Reagents.Angewandte Chemie (International ed. in English) · 2019Article
- Convergent Total Synthesis of Principinol D, a Rearranged Kaurane Diterpenoid.Journal of the American Chemical Society · 2019Article
- Scalable synthesis enabling multilevel bio-evaluations of natural products for discovery of lead compounds.Nature communications · 2018Article
- Total synthesis of complex terpenoids employing radical cascade processes.Natural product reports · 2018Review
- Synthesis of azasilacyclopentenes and silanolsChemical science · 2017Article
- Recent Advances in Substrate-Controlled Asymmetric Cyclization for Natural Product Synthesis.Molecules (Basel, Switzerland) · 2017Review
- Synthesis of Functionalized Dihydrobenzofurans by Direct Aryl C-O Bond Formation under Mild Conditions.Angewandte Chemie (International ed. in English) · 2016Article
- 11-Step Total Synthesis of (-)-Maoecrystal V.Journal of the American Chemical Society · 2016Article
- Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.Angewandte Chemie (International ed. in English) · 2016Review
- The synthesis of functionalized bridged polycycles via C-H bond insertion.Beilstein journal of organic chemistry · 2016Review
- 10-Step Asymmetric Total Synthesis and Stereochemical Elucidation of (+)-Dragmacidin D.Angewandte Chemie (International ed. in English) · 2015Article
- The daphniphyllum alkaloids: total synthesis of (-)-calyciphylline N.Journal of the American Chemical Society · 2015Article
- Enantioselective synthesis of (-)-maoecrystal V by enantiodetermining C-H functionalization.Journal of the American Chemical Society · 2014Article
- Applications of C-H functionalization logic to cyclobutane synthesis.The Journal of organic chemistry · 2014Article
- Total synthesis of (-)-calyciphylline N.Journal of the American Chemical Society · 2014Article
- Cross-coupling of remote meta-C-H bonds directed by a U-shaped template.Journal of the American Chemical Society · 2013Article
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3 authors.
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Abstract
A total synthesis of the unusual ent-kaurane maoecrystal V is described. The synthesis strategy features a counterintuitive early disconnection of the lactone subunit to a polycyclic enol ether intermediate in order to preserve the central tetrahydrofuran ring until the beginning stages of the synthesis. This strategy enables an application of C-H functionalization at the early phase of the synthesis during the construction of a dihydrobenzofuran intermediate.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.