Evidence map›Paper›PMID 24000186›Full record

ArticleAngewandte Chemie (International ed. in English)2013

Selective intermolecular amination of C-H bonds at tertiary carbon centers.

Jennifer L Roizen, David N Zalatan, J Du Bois

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 40 papers.

0numbers the graph read from it
0cells of the map it votes in
40citing papers in PubMed
4.9field-weighted citation impact, top 4% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

40 citing papers in PubMed, 144 citations in OpenAlex.

  1. Article
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  8. Article
  9. Aspartyl β-Turn-Based Dirhodium(II) Metallopeptides for Benzylic C(spJournal of the American Chemical Society · 2023
    Article
  10. Photoredox-Nickel Dual-CatalyzedJournal of the American Chemical Society · 2023
    Article
  11. Article
  12. Silver Catalyzed Site-Selective C(spMolecules (Basel, Switzerland) · 2022
    Article
  13. Article
  14. Article
  15. Article
  16. Article
  17. Late-Stage Diversification: A Motivating Force in Organic Synthesis.Journal of the American Chemical Society · 2021
    Article
  18. Article
  19. Article
  20. Site Selective Chlorination of C(spAngewandte Chemie (International ed. in English) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 2 institutions in 1 country.

Jennifer L RoizenDepartment of Chemistry, Duke University, 3236 French Science Center, 124 Science Drive, Durham, NC 27708-0346 (USA).
David N Zalatan
J Du Bois
Stanford University · USDuke University · US

Funding

Tools to Fight Cancer: Exploiting Heck-type Olefinations to Forge Medium RingsF32GM089033 · NIGMS · STANFORD UNIVERSITY · PI ROIZEN, JENNIFER L · 2009 to 2012
$146k
NIGMS NIH HHS F32 GM089033NIGMS NIH HHS F32GM089033
6 · The paper itself

Abstract

C-H insertion: A method for intermolecular amination of tertiary CH bonds is described that uses limiting amounts of substrate and a convenient phenol-derived nitrogen source. Structure-selectivity and mechanistic studies suggest that steric interaction between the substrate and active oxidant is the principal determinant of product selectivity.

Indexed as

AminationAminesCarbonHydrogenRhodiumStereoisomerismAminesCarbonHydrogenRhodiumaminationaminesC-H insertionisotope effectrhodium

Identifiers

PMID24000186
PMCPMC5483380
OpenAlexW2153484069

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.