ArticleJournal of the American Chemical Society2013
Gold(I)-catalyzed enantioselective carboalkoxylation of alkynes.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 99 citations in OpenAlex.
- Synthesis of 5-Hydrazino-2-cyclopentenone Derivatives by a Gold(I)-Catalyzed Cycloisomerization/Hetero-Diels-Alder/Ring-Opening Tandem Reaction of Enynyl Acetates.The Journal of organic chemistry · 2023Article
- Recent Advances in Gold(I)-Catalyzed Approaches to Three-Type Small-Molecule Scaffolds via Arylalkyne Activation.Molecules (Basel, Switzerland) · 2022Review
- Coinage Metal-Catalyzed Asymmetric Reactions ofMolecules (Basel, Switzerland) · 2022Review
- Au(III) complexes with tetradentate-cyclam-based ligands.Beilstein journal of organic chemistry · 2021Article
- Synthesis of Chiral Bifunctional NHC Ligands and Survey of Their Utilities in Asymmetric Gold Catalysis.Organometallics · 2019Article
- Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement.Nature communications · 2019Article
- A Cooperative Hydrogen Bond Donor-Brønsted Acid System for the Enantioselective Synthesis of Tetrahydropyrans.Angewandte Chemie (International ed. in English) · 2018Article
- Rh-catalyzed Reagent-Free Ring Expansion of Cyclobutenones and Benzocyclobutenones.Chemical science · 2015Article
- One-Pot Cannizzaro Cascade Synthesis of ortho-Fused Cycloocta-2,5-dien-1-ones from 2-Bromo(hetero)aryl Aldehydes.Angewandte Chemie (International ed. in English) · 2015Article
- Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement.Angewandte Chemie (International ed. in English) · 2015Article
- Gold(I)-catalyzed dearomative Rautenstrauch rearrangement: enantioselective access to cyclopenta[b]indoles.Journal of the American Chemical Society · 2015Article
- 1,2-N-migration in a gold-catalysed synthesis of functionalised indenes by the 1,1-carboalkoxylation of ynamides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2014Article
- Stereoselective Synthesis of Trisubstituted Vinyl Bromides by Addition of Alkynes to Oxocarbenium Ions.Synlett : accounts and rapid communications in synthetic organic chemistryArticle
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
A highly enantioselective carboalkoxylation of alkynes catalyzed by cationic (DTBM-MeO-Biphep)gold(I) complexes is reported. Various optically active β-alkoxyindanone derivatives were obtained in good yields with high enantioselectivities. Furthermore, this methodology was extended to the enantioselective synthesis of 3-methoxycyclopentenones. The reaction is proposed to proceed through an enantioselective cyclization of intermediates containing vinylgold(I) and prochiral oxocarbenium moieties.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.