ArticleJournal of the American Chemical Society2013
Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 29 papers.
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Who cites it
29 citing papers in PubMed.
- Secondary-sphere hydrogen bonding promotes catalytic nitrate reduction at iron.Nature chemistry · 2026Article
- Influence of Transition-Metal Ions on the Photoisomerization of a Pentadentate Azopyridine Ligand: Interplay of Charge-Transfer and Metal-Centered States.Inorganic chemistry · 2026Article
- Article
- The Unique Role of the Second Coordination Sphere to Unlock and Control Catalysis in Nonheme Fe(II)/2-Oxoglutarate Histone Demethylase KDM2A.Inorganic chemistry · 2024Article
- Selective Metal-ion Complexation of a Biomimetic Calix[6]arene Funnel Cavity Functionalized with Phenol or Quinone.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Homoprotocatechuate dioxygenase active site: Imitating the secondary sphere base via computational design.Turkish journal of chemistry · 2023Article
- Rhodium(i) complexes derived from tris(isopropyl)-azaphosphatrane-controlling the metal-ligand interplay.RSC advances · 2021Article
- Efficient Synthesis of 6,6´-Diamido-2,2´-dipicolylamine Ligands for Potential Phosphate Anion Sensing.New journal of chemistry = Nouveau journal de chimie · 2021Article
- Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex.Angewandte Chemie (International ed. in English) · 2021Article
- Aromatic foldamers as scaffolds for metal second coordination sphere design.Chemical science · 2020Article
- Mononuclear, Nonheme, High-Spin {FeNO}Inorganic chemistry · 2019Article
- Unravelling mechanistic features of organocatalysis with in situ modifications at the secondary sphere.Nature chemistry · 2019Article
- Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions.ACS central science · 2019Review
- Selective C-H halogenation over hydroxylation by non-heme iron(iv)-oxo.Chemical science · 2018Article
- Quantum Mechanics/Molecular Mechanics Studies on the Relative Reactivities of Compound I and II in Cytochrome P450 Enzymes.International journal of molecular sciences · 2018Article
- Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex.Journal of the American Chemical Society · 2018Article
- Selectivity of C-H versus C-F Bond Oxygenation by Homo- and Heterometallic FeChemistry (Weinheim an der Bergstrasse, Germany) · 2017Article
- Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in FeAngewandte Chemie (International ed. in English) · 2017Article
- Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations.Journal of the American Chemical Society · 2016Article
- Mono- and binuclear non-heme iron chemistry from a theoretical perspective.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2016Review
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8 authors.
Funding
Abstract
The new biomimetic ligands N4Py(2Ph) (1) and N4Py(2Ph,amide) (2) were synthesized and yield the iron(II) complexes [Fe(II)(N4Py(2Ph))(NCCH3)](BF4)2 (3) and [Fe(II)(N4Py(2Ph,amide))](BF4)2 (5). Controlled orientation of the Ph substituents in 3 leads to facile triplet spin reactivity for a putative Fe(IV)(O) intermediate, resulting in rapid arene hydroxylation. Addition of a peripheral amide substituent within hydrogen-bond distance of the iron first coordination sphere leads to stabilization of a high-spin Fe(III)OOR species which decays without arene hydroxylation. These results provide new insights regarding the impact of secondary coordination sphere effects at nonheme iron centers.
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