Evidence map›Paper›PMID 23824208›Full record

ArticleDalton transactions (Cambridge, England : 2003)2013

Novel rhenium(III, IV, and V) tetradentate N2O2 Schiff base mononuclear and dinuclear complexes.

David A Rotsch, Kimberly M Reinig, Eric M Weis, Anna B Taylor, Charles L Barnes, Silvia S Jurisson

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Dalton transactions (Cambridge, England : 2003), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

David A RotschDepartment of Chemistry, University of Missouri-Columbia, Columbia, MO 65211, USA.
Kimberly M Reinig
Eric M Weis
Anna B Taylor
Charles L Barnes
Silvia S Jurisson

Funding

800 MHZ SPECTROMETER FOR BIOMOLECULAR NMR: STRUCTURAL BIOLOGYS10RR022341 · NCRR · UNIVERSITY OF MISSOURI-COLUMBIA · PI VAN DOREN, STEVEN R · 2006 to 2006
$500k
UPGRADE OF A WIDEBORE 300 MHZ SPECTROMETERS10RR011962 · NCRR · UNIVERSITY OF MISSOURI-COLUMBIA · PI HARDIN, CHRISTOPHER D · 1997 to 1997
–
NCRR NIH HHS 1S10RR11962-01NCRR NIH HHS S10 RR022341NCRR NIH HHS S10 RR022341-01
6 · The paper itself

Abstract

Reaction of (Bu4N)[ReOCl4] with the tetradentate Schiff base ligand α,α'-[(1,1-dimethylethylene)dinitrilo]di-o-cresol (sal2ibnH2) yields cis-[Re(V)OCl(sal2ibn)], which quickly forms trans-[μ-O(Re(V)O(sal2ibn))2] in solution. The dinuclear complex can also be isolated by the addition of base (Et3N) to the reaction mixture. Conversely, the mononuclear complex can be trapped as cis-[Re(V)O(NCS)(sal2ibn)] by addition of (Bu4N)SCN to the reaction mixture. Reduction of cis-[Re(V)O(NCS)sal2ibn] with triphenylphosphine gives the rare trans-[Re(III)(NCS)(PPh3)(sal2ibn)] and unique μ-oxo Re(IV) dimer trans-[μ-O(Re(IV)(NCS)(sal2ibn))2]. All of the complexes were characterized by (1)H and (13)C NMR, FT-IR spectroscopy, electrospray ionization mass spectrometry (ESI-MS), cyclic voltammetry and single crystal X-ray diffraction.

Indexed as

Models, MolecularMolecular ConformationNitrogen OxidesOrganometallic CompoundsRheniumSchiff BasesStereoisomerismNitrogen OxidesOrganometallic CompoundsRheniumSchiff Bases

Identifiers

PMID23824208
PMCPMC3777258

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.