ArticleJournal of the American Chemical Society2013
Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
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Who cites it
27 citing papers in PubMed, 104 citations in OpenAlex.
- Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids.JACS Au · 2024Review
- Mechanistic Insights into Nitrile Activation by Cobalt(III)-Hydroperoxo Intermediates: The Influence of Ligand Basicity.JACS Au · 2023Article
- ScJournal of the American Chemical Society · 2020Article
- Harnessing the active site triad: merging hemilability, proton responsivity, and ligand-based redox-activity.Dalton transactions (Cambridge, England : 2003) · 2020Article
- The Generation of the Oxidant Agent of a Mononuclear Nonheme Fe(II) Biomimetic Complex by Oxidative Decarboxylation. A DFT Investigation.Molecules (Basel, Switzerland) · 2020Article
- Activation of a Non-Heme FeAngewandte Chemie (International ed. in English) · 2019Article
- Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/OChemical reviews · 2019Review
- Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic MnInorganic chemistry · 2019Article
- HACS catalysis · 2018Article
- Uncoupled Redox-Inactive Lewis Acids in the Secondary Coordination Sphere Entice Ligand-Based Nitrite Reduction.Inorganic chemistry · 2018Article
- Diiron monooxygenases in natural product biosynthesis.Natural product reports · 2018Review
- ScJournal of the American Chemical Society · 2018Article
- Unprecedented (μ-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI.Journal of the American Chemical Society · 2017Article
- Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive LJournal of the American Chemical Society · 2017Article
- Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective.Journal of the American Chemical Society · 2016Review
- Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine.Inorganic chemistry · 2016Article
- Tuning the Redox Properties of a Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Zinc Ions by Water Molecules.Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
- Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.Journal of the American Chemical Society · 2015Article
- An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway.Journal of the American Chemical Society · 2015Article
- Investigations of the effect of the non-manganese metal in heterometallic-oxido cluster models of the oxygen evolving complex of photosystem II: lanthanides as substitutes for calcium.Inorganic chemistry · 2015Article
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Authors and funding
5 authors at 2 institutions in 1 country.
Funding
Abstract
We report that redox-inactive Sc(3+) can trigger O2 activation by the Fe(II)(TMC) center (TMC = tetramethylcyclam) to generate the corresponding oxoiron(IV) complex in the presence of BPh4(-) as an electron donor. To model a possible intermediate in the above reaction, we generated an unprecedented Sc(3+) adduct of [Fe(III)(η(2)-O2)(TMC)](+) by an alternative route, which was found to have an Fe(3+)-(μ-η(2):η(2)-peroxo)-Sc(3+) core and to convert to the oxoiron(IV) complex. These results have important implications for the role a Lewis acid can play in facilitating O-O bond cleavage during the course of O2 activation at non-heme iron centers.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.