ArticleJournal of the American Chemical Society2013
Synthesis of highly cis, syndiotactic polymers via ring-opening metathesis polymerization using ruthenium metathesis catalysts.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Leveraging Mechanistic Insights into Stereoretentive ROMP for Precision Synthesis of Poly(Journal of the American Chemical Society · 2026Article
- Chiral poly(aza-norbornene) derivatives with tunable tacticity and living ROMP capability.Chemical science · 2026Article
- Article
- Recent advances in ruthenium-based olefin metathesis.Chemical Society reviews · 2018Review
- Copolymerization of Norbornene and Norbornadiene Using a cis-Selective Bimetallic W-Based Catalytic System.Polymers · 2017Article
- Cationic ruthenium alkylidene catalysts bearing phosphine ligands.Dalton transactions (Cambridge, England : 2003) · 2016Article
- Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols.Angewandte Chemie (International ed. in English) · 2015Article
- Recent advances in metathesis-derived polymers containing transition metals in the side chain.Beilstein journal of organic chemistry · 2015Review
- Self-assembly of random copolymers.Chemical communications (Cambridge, England) · 2014Article
- Enantioselective olefin metathesis with cyclometalated ruthenium complexes.Journal of the American Chemical Society · 2014Article
- Carboxylate-assisted C(sp³)-H activation in olefin metathesis-relevant ruthenium complexes.Journal of the American Chemical Society · 2014Article
- General approach to the synthesis of the chlorosulfolipids danicalipin A, mytilipin A, and malhamensilipin A in enantioenriched form.The Journal of organic chemistry · 2014Article
- Ruthenium-catalysedChemical science · 2014Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.