ArticleThe Journal of organic chemistry2013
Nickel-catalyzed borylation of halides and pseudohalides with tetrahydroxydiboron [B2(OH)4].
Article in The Journal of organic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Flash Communication: Siloxides Promote the Iron-Catalyzed Borylation of Aryl Chlorides.Organometallics · 2026Article
- Borylation of Aryl Halides Induced by Visible Light Under Open-To-Air Environment.ChemSusChem · 2026Article
- Article
- Iron-Catalyzed Miyaura Borylation of Aryl Chlorides and Triflates.Organic letters · 2025Article
- Isolation and Reactivity of Arylnickel(II) Complexes in Nickel-Catalyzed Borylation of Aryl Fluorosulfates.JACS Au · 2024Article
- Pd-Catalyzed Difluoromethylations of Aryl Boronic Acids, Halides, and Pseudohalides with ICFChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.Chemical reviews · 2022Review
- Ni-Catalyzed Borylation of Aryl Sulfoxides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Organoboron chemistry comes to light: recent advances in photoinduced synthetic approaches to organoboron compounds.Tetrahedron · 2019Article
- Direct Transformation from Arylamines to Aryl Naphthalene-1,8-diamino Boronamides: A Metal-Free Sandmeyer-Type Process.Molecules (Basel, Switzerland) · 2019Article
- Brush-First and ROMP-Out with Functional (Macro)monomers: Method Development, Structural Investigations, and Applications of an Expanded Brush-Arm Star Polymer Platform.Macromolecules · 2018Article
- Article
- B(MIDA)-Containing Diborons.ACS omega · 2017Article
- Convenient and General Zinc-Catalyzed Borylation of Aryl Diazonium Salts and Aryltriazenes under Mild Conditions.ChemistryOpen · 2017Article
- 3-Cyanoallyl boronates are versatile building blocks in the synthesis of polysubstituted thiophenes.Chemical science · 2017Article
- Well-defined nickel and palladium precatalysts for cross-coupling.Nature reviews. Chemistry · 2017Article
- Crystal structure of 2-isopropyl-5,7'-dimethyl-1',3',3a',6',8a',8b'-hexa-hydro-spiro-[cyclo-hexane-1,6'-furo[3,4-d]imidazo[1,5-b]isoxazol]-8'(7'H)-one.Acta crystallographica. Section E, Crystallographic communications · 2016Article
- Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions.Chemical science · 2016Article
- Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts.Journal of the American Chemical Society · 2016Article
- A modified procedure for the palladium catalyzed borylation/Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides utilizing bis-boronic acid.Tetrahedron · 2015Article
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3 authors.
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Abstract
Arylboronic acids are gaining increased importance as reagents and target structures in a variety of useful applications. Recently, the palladium-catalyzed synthesis of arylboronic acids employing the atom-economical tetrahydroxydiboron (BBA) reagent has been reported. The high cost associated with palladium, combined with several limitations of both palladium- and copper-catalyzed processes, prompted us to develop an alternative method. Thus, the nickel-catalyzed borylation of aryl and heteroaryl halides and pseudohalides using tetrahydroxydiboron (BBA) has been formulated. The reaction proved to be widely functional group tolerant and applicable to a number of heterocyclic systems. To the best of our knowledge, the examples presented here represent the only effective Ni-catalyzed Miyaura borylations conducted at room temperature.
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