ArticleOrganic letters2013
Copper-catalyzed oxidative Heck reactions between alkyltrifluoroborates and vinyl arenes.
Article in Organic letters, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Cobaloxime-catalysed regiodivergent hydrogen atom transfer for alkenyl and allylic carbamoylation with branched alkenes.Nature communications · 2026Article
- Photocatalysis Enables Chemodivergent Radical Polar Crossover: Ritter-Type Amidation vs Heck-Type Olefin Carbofunctionalizations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Enantioenriched Allylesters via a Copper-Catalyzed Diene Carboesterification with Alkyltrifluoroborates and Carboxylic Acids.The Journal of organic chemistry · 2024Article
- Hybrid PdFrontiers in chemistry · 2024Article
- Contrasteric coupling of allenes and tetrahydroisoquinolines by iron-catalysed allenic C(spChemical communications (Cambridge, England) · 2021Article
- Synthesis of Benzylureas and Related Amine Derivatives via Copper-Catalyzed Three-Component Carboamination of Styrenes.Organic letters · 2020Article
- Saturated oxygen and nitrogen heterocyclesChemical science · 2019Article
- Transition-Metal-Catalyzed Alkyl Heck-Type Reactions.Synthesis · 2019Article
- Vinylation of Benzylic Amines via C-N Bond Functionalization of Benzylic Pyridinium Salts.Synthesis · 2018Article
- Stereoselective and Regioselective Synthesis of Heterocycles via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes.The Journal of organic chemistry · 2017Article
- Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters.Chemistry (Weinheim an der Bergstrasse, Germany) · 2016Article
- Synthesis of 2-Aryl- and 2-Vinylpyrrolidines via Copper-Catalyzed Coupling of Styrenes and Dienes with Potassium β-Aminoethyl Trifluoroborates.Organic letters · 2016Article
- Enantioselective copper-catalyzed carboetherification of unactivated alkenes.Angewandte Chemie (International ed. in English) · 2014Article
- Allylic functionalization of unactivated olefins with Grignard reagents.Angewandte Chemie (International ed. in English) · 2014Article
- Palladium-Catalyzed Cross-Coupling of α-Bromocarbonyls and Allylic Alcohols for the Synthesis of α-Aryl Dicarbonyl Compounds.Chemical scienceArticle
- Copper-Catalyzed Synthesis ofSynlett : accounts and rapid communications in synthetic organic chemistryArticle
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
We report herein that potassium alkyltrifluoroborates can be utilized in oxidative Heck-type reactions with vinyl arenes. The reaction is catalyzed by a Cu(OTf)2/1,10-phenanthroline with MnO2 as the stoichiometric oxidant. In addition to the alkyl Heck, amination, esterification, and dimerization reactions of alkyltrifluoroborates are demonstrated under analogous reaction conditions. Evidence for an alkyl radical intermediate is presented.
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