ArticleJournal of the American Chemical Society2013
Temperature-sensitive transitions below LCST in amphiphilic dendritic assemblies: host-guest implications.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Molecular bases for temperature sensitivity in supramolecular assemblies and their applications as thermoresponsive soft materials.Materials horizons · 2022Review
- Supramolecular Self-Associations of Amphiphilic Dendrons and Their Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
- Simple Regulation of the Self-Assembling Ability by Multimerization of Elastin-Derived Peptide (FPGVG)ACS omega · 2021Article
- An Azobenzene-Based Single-Component Supramolecular Polymer Responsive to Multiple Stimuli in Water.Journal of the American Chemical Society · 2020Article
- Insights into the Kinetics of Supramolecular Comonomer Incorporation in Water.Macromolecules · 2019Article
- Role of Aromatic Interactions in Temperature-Sensitive Amphiphilic Supramolecular Assemblies.Langmuir : the ACS journal of surfaces and colloids · 2016Article
- Expression of CD11c Is Associated with Unconventional Activated T Cell Subsets with High Migratory Potential.PloS one · 2016Article
- Influence of backbone conformational rigidity in temperature-sensitive amphiphilic supramolecular assemblies.Journal of the American Chemical Society · 2015Article
- Activatable DendriticACS macro letters · 2015Article
- Experimental and theoretical investigations in stimuli responsive dendrimer-based assemblies.Nanoscale · 2015Review
- Tuning thermoresponsive supramolecular G-quadruplexes.Langmuir : the ACS journal of surfaces and colloids · 2015Article
- Stimuli-responsive nanomaterials for biomedical applications.Journal of the American Chemical Society · 2015Article
- Environment-dependent guest exchange in supramolecular hosts.Langmuir : the ACS journal of surfaces and colloids · 2014Article
- Supramolecular disassembly of facially amphiphilic dendrimer assemblies in response to physical, chemical, and biological stimuli.Accounts of chemical research · 2014Article
- Protein and enzyme gated supramolecular disassembly.Journal of the American Chemical Society · 2014Article
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Authors and funding
6 authors.
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Abstract
Oligo(ethylene glycol)-decorated supramolecular assemblies have been of great interest due to their charge-neutral character and thus their propensity to avoid nonspecific interactions. These systems are known to exhibit a macroscopic temperature-sensitive transition, where the assembly phase-separates from the aqueous phase at higher temperatures. While this so-called lower critical solution temperature (LCST) behavior has been well-studied, there have been no studies on the fate of these supramolecular assemblies below this transition temperature. The work here brings to light the presence of a second, sub-LCST transition, observed well below the LCST of oligo(ethylene glycol) (OEG)-based dendrons, where the host-guest properties of the assembly are significantly altered. This sub-LCST transition is accompanied by changes in the guest encapsulation stability and dynamics of host exchange.
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