ArticleJournal of magnetic resonance (San Diego, Calif. : 1997)2013
A general method for diagonal peak suppression in homonuclear correlated NMR spectra by spatially and frequency selective pulses.
Article in Journal of magnetic resonance (San Diego, Calif. : 1997), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Article
- Extracting unresolved coupling constants from complex multiplets by a real-time J-upscaled SERF experiment.Magnetic resonance in chemistry : MRC · 2018Article
- Perfecting band selective homo-decoupling for decoupling two signals coupled within the same band.RSC advances · 2018Article
- Spin-echo based diagonal peak suppression in solid-state MAS NMR homonuclear chemical shift correlation spectra.Journal of magnetic resonance (San Diego, Calif. : 1997) · 2018Article
- Directly decoupled diffusion-ordered NMR spectroscopy for the analysis of compound mixtures.Chemistry (Weinheim an der Bergstrasse, Germany) · 2014Article
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Authors and funding
3 authors.
Funding
Abstract
Homonuclear two- and multidimensional NMR spectra are standard experiments for the structure determination of small to medium-sized molecules. In the large majority of homonuclear correlated spectra the diagonal contains the most intense peaks. Cross-peaks near the diagonal could overlap with huge tails of diagonal peaks and can therefore be easily overlooked. Here we present a general method for the suppression of peaks along the diagonal in homonuclear correlated spectra. It is based on a spatially selective excitation followed by the suppression of magnetization which has not changed the frequency during the mixing process. In addition to the auto correlation removal, these experiments are also less affected by magnetic field inhomogeneities due to the slice selective excitation, which on the other side leads to a reduced intensity compared to regular homonuclear correlated spectra.
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