ArticleJournal of the American Chemical Society2013
Enantioselective thiourea-catalyzed intramolecular cope-type hydroamination.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
27 citing papers in PubMed.
- Regio-reversed alkenyl-arylation of ynamidesChemical science · 2026Article
- Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques.ACS catalysis · 2022Article
- Alcohols as Alkylating Agents in the Cation-Induced Formation of Nitrogen Heterocycles.Angewandte Chemie (International ed. in English) · 2022Article
- A redox-enabled strategy for intramolecular hydroamination.Chemical science · 2022Article
- Electrophilic Aminating Agents in Total Synthesis.Angewandte Chemie (International ed. in English) · 2021Review
- Tunable and Cooperative Catalysis for Enantioselective Pictet-Spengler Reaction with Varied Nitrogen-Containing Heterocyclic Carboxaldehydes.Angewandte Chemie (International ed. in English) · 2021Article
- Brønsted acid-promoted hydroamination of unsaturated hydrazones: access to biologically important 5-arylpyrazolines.RSC advances · 2021Article
- Desymmetrization of unactivated bis-alkenesChemical science · 2020Article
- Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer.Journal of the American Chemical Society · 2020Article
- Enantioselective Catalysis of an Anionic Oxy-Cope Rearrangement Enabled by Synergistic Ion Binding.Israel journal of chemistry · 2020Article
- Chiral Thioureas-Preparation and Significance in Asymmetric Synthesis and Medicinal Chemistry.Molecules (Basel, Switzerland) · 2020Review
- Electrochemistry and Photoredox Catalysis: A Comparative Evaluation in Organic Synthesis.Molecules (Basel, Switzerland) · 2019Review
- Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles.Angewandte Chemie (International ed. in English) · 2019Article
- 3-Aryl-2,5-Dihydropyrroles via Catalytic Carbonyl-Olefin Metathesis.ACS catalysis · 2018Article
- Stereoselective and Regioselective Synthesis of Heterocycles via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes.The Journal of organic chemistry · 2017Article
- CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters - a computational scrutiny of rival mechanistic pathways.Chemical science · 2017Article
- Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling.Angewandte Chemie (International ed. in English) · 2017Article
- Enantioselective Aza-Sakurai Cyclizations: Dual Role of Thiourea as H-Bond Donor and Lewis Base.Journal of the American Chemical Society · 2016Article
- The Cation-π Interaction in Small-Molecule Catalysis.Angewandte Chemie (International ed. in English) · 2016Review
- Nucleophile-Assisted Alkene Activation: Olefins Alone Are Often Incompetent.Journal of the American Chemical Society · 2016Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Catalysis of Cope-type rearrangements of bis-homoallylic hydroxylamines is demonstrated using chiral thiourea derivatives. This formal intramolecular hydroamination reaction provides access to highly enantioenriched α-substituted pyrrolidine products and represents a complementary approach to metal-catalyzed methods.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.