ArticleOrganic letters2013
Complementary regioselectivity in Rh(III)-catalyzed insertions of potassium vinyltrifluoroborate via C-H activation: preparation and use of 4-trifluoroboratotetrahydroisoquinolones.
Article in Organic letters, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
17 citing papers in PubMed.
- Mechanistic Insights into the Reductive N-O Bond Cleavage ofACS organic & inorganic Au · 2025Article
- Three-component 1,2-carboamination of vinyl boronic estersChemical science · 2021Article
- Article
- RhChemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- From Pd(OAc)Accounts of chemical research · 2020Article
- Rhodium catalyzed template-assisted distalChemical science · 2019Article
- Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study.Journal of the American Chemical Society · 2017Article
- Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction.Journal of the American Chemical Society · 2016Article
- Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions.Chemical reviews · 2016Review
- A Simple and Versatile Amide Directing Group for C-H Functionalizations.Angewandte Chemie (International ed. in English) · 2016Review
- Expeditious Synthesis of Isoquinolones and Isocoumarins with a Vinyl Borane as an Acetylene Equivalent.European journal of organic chemistry · 2016Article
- Pd(II)-catalyzed C-H functionalizations directed by distal weakly coordinating functional groups.Journal of the American Chemical Society · 2015Article
- Rh(iii)-catalyzed C-H olefination ofChemical science · 2015Article
- Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones.Chemical science · 2015Article
- Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate.The Journal of organic chemistry · 2013Review
- Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes.Synlett : accounts and rapid communications in synthetic organic chemistry · 2013Article
- Ligand-AcceleratedOrganic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicalsArticle
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
Abstract
Potassium vinyltrifluoroborate was found to be an efficient partner with benzamide derivatives for Rh(III)-catalyzed annulations. 4-Trifluoroboratotetrahydroisoquinolones were generated under mild conditions, affording a regioisomerically complementary substitution pattern to other alkenes in related reactions. These new boron-containing building blocks were derivatized by N-arylations, retaining the boron substituent for further elaboration.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.