ArticleNature communications2013
Excitation-dependent visible fluorescence in decameric nanoparticles with monoacylglycerol cluster chromophores.
Article in Nature communications, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Glass formation of metal organic-inorganic complexes.National science review · 2026Article
- Underlying charge-transfer mechanism of visible light emission in guanine crystals.Communications chemistry · 2025Article
- Controllable multicolor emission from initially non-emissive organic molecules by pressure engineering.Nature communications · 2025Article
- Molecular-level enhanced clusterization-triggered emission of nonconventional luminophores in dilute aqueous solution.Nature communications · 2023Article
- Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer.Nature communications · 2020Article
- A clustering-triggered emission strategy for tunable multicolor persistent phosphorescence.Chemical science · 2020Article
- Microwave-Assisted One-Pot Synthesis of Indole-Based Fluorescent Probe for Sensitive Detection of Copper (II).Journal of fluorescence · 2020Article
- Excitation-dependent fluorescence from atomic/molecular layer deposited sodium-uracil thin films.Scientific reports · 2017Article
- Synthesis and Characterization of Dual-Sensitive Fluorescent Nanogels for Enhancing Drug Delivery and Tracking Intracellular Drug Delivery.International journal of molecular sciences · 2017Article
- Plasmon-Modulated Excitation-Dependent Fluorescence from Activated CTAB Molecules Strongly Coupled to Gold Nanoparticles.Scientific reports · 2017Article
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Authors and funding
13 authors.
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Abstract
Organic fluorescent nanoparticles, excitation-dependent photoluminescence, hydrogen-bonded clusters and lysobisphosphatidic acid are four interesting individual topics in materials and biological sciences. They have attracted much attention not only because of their unique properties and important applications, but also because the nature of their intriguing phenomena remained unclear. Here we report a new type of organic fluorescent nanoparticles with intense blue and excitation-dependent visible fluorescence in the range of 410-620 nm. The nanoparticles are composed of ten bis(monoacylglycerol)bisphenol-A molecules and the self-assembly occurs only in elevated concentrations of 2-monoacylglycerol via radical-catalysed 3,2-acyl migration from 3-monoacylglycerol in neat conditions. The excitation-dependent fluorescence behaviour is caused by chromophores composed of hydrogen-bonded monoacylglycerol clusters, which are linked by an extensive hydrogen-bonding network between the ester carbonyl groups and the protons of the alcohols with collective proton motion and HO···C=O (n→π) interactions.
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