ArticleJournal of the American Chemical Society2013
Mechanism of assembly of the dimanganese-tyrosyl radical cofactor of class Ib ribonucleotide reductase: enzymatic generation of superoxide is required for tyrosine oxidation via a Mn(III)Mn(IV) intermediate.
Joseph A Cotruvo et al.PubMed ↗Full text ↗Publisher ↗
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