ArticleAngewandte Chemie (International ed. in English)2013
Catalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoates.
Article in Angewandte Chemie (International ed. in English), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Phosphine-Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3-Pyrrolines through Phosphonium Diene Intermediates.ChemCatChem · 2020Article
- Design, synthesis and application of a new type of bifunctionalChemical science · 2019Article
- Direct Catalytic Asymmetric Synthesis of Trifluoromethylated γ-Amino Esters/Lactones via Umpolung Strategy.The Journal of organic chemistry · 2019Article
- Phosphine Organocatalysis.Chemical reviews · 2018Review
- Bridged [2.2.1] bicyclic phosphine oxide facilitates catalytic γ-umpolung addition-Wittig olefination.Chemical science · 2018Article
- Catalytic Asymmetric Synthesis of Trifluoromethylated γ-Amino Acids through the Umpolung Addition of Trifluoromethyl Imines to Carboxylic Acid Derivatives.Angewandte Chemie (International ed. in English) · 2018Article
- Catalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H Bonds.Journal of the American Chemical Society · 2016Article
- Asymmetric cyanation of imines via dipeptide-derived organophosphine dual-reagent catalysis.Nature communications · 2016Article
- Phosphine-Catalyzed Intramolecular Cyclizations of α-Nitroethylallenoates Forming (Z)-Furanone Oximes.Organic letters · 2016Article
- 1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis.Beilstein journal of organic chemistry · 2016Review
- Asymmetric α-amination of 3-substituted oxindoles using chiral bifunctional phosphine catalysts.Beilstein journal of organic chemistry · 2016Article
- Phosphine-Mediated Iterative Arene Homologation Using Allenes.Journal of the American Chemical Society · 2015Article
- Highly enantioselective construction of tertiary thioethers and alcoholsChemical science · 2015Article
- Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives.Journal of the American Chemical Society · 2015Article
- Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates.Tetrahedron letters · 2015Article
- Use of a new spirophosphine to achieve catalytic enantioselective [4 + 1] annulations of amines with allenes to generate dihydropyrroles.Journal of the American Chemical Society · 2015Article
- Highly enantioselective, intermolecular hydroamination of allenyl esters catalyzed by bifunctional phosphinothioureas.Journal of the American Chemical Society · 2014Article
- The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.Natural product reports · 2014Review
- Chiral phosphines in nucleophilic organocatalysis.Beilstein journal of organic chemistry · 2014Review
- Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs.Chemical communications (Cambridge, England) · 2013Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Pin the amine on the gamma: A new method has been developed for the γ-addition of nitrogen nucleophiles to γ-substituted alkynoates or allenoates through intra- and intermolecular processes that are catalyzed by spirophosphine 1. An asymmetric version of this reaction affords enantioenriched pyrrolidines, indolines, and γ-amino-α,β-unsaturated carbonyl compounds.
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Registered trials
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