ArticleScientific reports2012
A singular thermodynamically consistent temperature at the origin of the anomalous behavior of liquid water.
Article in Scientific reports, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- New Considerations Around the Singular Water Temperature Explaining the Anomalous Behavior of Liquid Phase.International journal of molecular sciences · 2026Article
- Do Specific Ion Effects on Collective Relaxation Arise from Perturbation of Hydrogen-Bonding Network Structure?The journal of physical chemistry. B · 2024Article
- Article
- Combined Description of the Equation of State and Diffusion Coefficient of Liquid Water Using a Two-State Sanchez-Lacombe Approach.Molecules (Basel, Switzerland) · 2023Article
- The Hydrophobic Effect Studied by Using Interacting Colloidal Suspensions.International journal of molecular sciences · 2023Article
- From Critical Point to Critical Point: The Two-States Model Describes Liquid Water Self-Diffusion from 623 to 126 K.Molecules (Basel, Switzerland) · 2021Article
- Hydrophilic and Hydrophobic Effects on the Structure and Themodynamic Properties of Confined Water: Water in Solutions.International journal of molecular sciences · 2021Article
- Some Aspects of the Liquid Water Thermodynamic Behavior: From The Stable to the Deep Supercooled Regime.International journal of molecular sciences · 2020Article
- The Proton Density of States in Confined Water (HInternational journal of molecular sciences · 2019Article
- In Vivo Water Dynamics in Shewanella oneidensis Bacteria at High Pressure.Scientific reports · 2019Article
- The Role of Hydrogen Bonding in the Folding/Unfolding Process of Hydrated Lysozyme: A Review of Recent NMR and FTIR Results.International journal of molecular sciences · 2018Review
- Activity of Supercooled Water on the Ice Curve and Other Thermodynamic Properties of Liquid Water up to the Boiling Point at Standard Pressure.Journal of chemical and engineering data · 2018Article
- High-Temperature Dynamic Behavior in Bulk Liquid Water: A Molecular Dynamics Simulation Study using the OPC and TIP4P-Ew Potentials.Frontiers of physics · 2018Article
- Temperature-dependent optoacoustic response and transient through zero Grüneisen parameter in optically contrasted media.Photoacoustics · 2017Article
- Energy landscape in protein folding and unfolding.Proceedings of the National Academy of Sciences of the United States of America · 2016Article
- Experimental triplet and quadruplet fluctuation densities and spatial distribution function integrals for pure liquids.The Journal of chemical physics · 2015Article
- The role of water in protein's behavior: The two dynamical crossovers studied by NMR and FTIR techniques.Computational and structural biotechnology journal · 2015Article
Corrections and comments
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Authors and funding
3 authors.
Funding
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Abstract
The density maximum of water dominates the thermodynamics of the system under ambient conditions, is strongly P-dependent, and disappears at a crossover pressure P(cross) ~ 1.8 kbar. We study this variable across a wide area of the T-P phase diagram. We consider old and new data of both the isothermal compressibility K(T)(T, P) and the coefficient of thermal expansion α(P)(T, P). We observe that K(T)(T) shows a minimum at T* ~ 315±5 K for all the studied pressures. We find the behavior of α(P) to also be surprising: all the α(P)(T) curves measured at different P cross at T*. The experimental data show a "singular and universal expansivity point" at T* ~ 315 K and α(P)(T*) ≃ 0.44 10(-3) K(-1). Unlike other water singularities, we find this temperature to be thermodynamically consistent in the relationship connecting the two response functions.
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