ArticleJournal of the American Chemical Society2013
Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters.
Article in Journal of the American Chemical Society, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
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Who cites it
27 citing papers in PubMed.
- Silver-Free C-H Activation: Strategic Approaches towards Realizing the Full Potential of C-H Activation in Sustainable Organic Synthesis.Angewandte Chemie (International ed. in English) · 2022Review
- Copper Foam as Active Catalysts for the Borylation ofInternational journal of molecular sciences · 2022Article
- Cationic palladium(ii)-catalyzed synthesis of substituted pyridines from α,β-unsaturated oxime ethers.RSC advances · 2022Article
- Rh(iii)-Catalyzed [5 + 1] annulation of 2-alkenylanilides and 2-alkenylphenols with allenyl acetates.Chemical science · 2022Article
- Electrooxidative Rhodium-Catalyzed [5+2] Annulations via C-H/O-H Activations.Angewandte Chemie (International ed. in English) · 2021Article
- Functionalization of C-H bonds in acetophenone oximes with arylacetic acids and elemental sulfur.RSC advances · 2020Article
- Chiral cyclopentadienyl RhChemical science · 2019Article
- Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization.Accounts of chemical research · 2018Review
- Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study.Journal of the American Chemical Society · 2017Article
- Unified synthesis of mono/bis-arylated phenolsChemical science · 2017Article
- Rh(III)-Catalyzed C-H Bond Addition/Amine-Mediated Cyclization of Bis-Michael Acceptors.Organic letters · 2016Article
- Convergent Synthesis of Diverse Nitrogen Heterocycles via Rh(III)-Catalyzed C-H Conjugate Addition/Cyclization Reactions.Organic letters · 2016Article
- Article
- Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation.Journal of the American Chemical Society · 2015Article
- Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes.Synlett : accounts and rapid communications in synthetic organic chemistry · 2015Article
- Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines.Organic letters · 2015Article
- Rhodium-catalyzed C-H functionalization-based approach to eight-membered lactams.Chemical science · 2015Article
- Copper-mediated synthesis of N-alkenyl-α,β-unsaturated nitrones and their conversion to tri- and tetrasubstituted pyridines.Beilstein journal of organic chemistry · 2015Article
- Convergent Synthesis of Diverse Tetrahydropyridines via Rh(I)-Catalyzed C-H Functionalization Sequences.Organic process research & development · 2014Review
- Cobalt-catalyzed, aminoquinoline-directed coupling of sp(2) C-H bonds with alkenes.Organic letters · 2014Article
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Funding
Abstract
α,β-Unsaturated O-pivaloyl oximes are coupled to alkenes by Rh(III) catalysis to afford substituted pyridines. The reaction with activated alkenes is exceptionally regioselective and high-yielding. Mechanistic studies suggest that heterocycle formation proceeds via reversible C-H activation, alkene insertion, and a C-N bond formation/N-O bond cleavage process.
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