Evidence map›Paper›PMID 23172717›Full record

ArticleAngewandte Chemie (International ed. in English)2013

Cascade approach to stereoselective polycyclic ether formation: epoxides as trapping agents in the transposition of allylic alcohols.

Youwei Xie, Paul E Floreancig

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. A Formal Rearrangement of Allylic Silanols.Molecules (Basel, Switzerland) · 2021
    Article
  3. Article
  4. ReOrganic letters · 2019
    Article
  5. Diarylmethane synthesis through ReChemical science · 2018
    Article
  6. ReAngewandte Chemie (International ed. in English) · 2017
    Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Youwei XieDepartment of Chemistry, University of Pittsburgh, PA 15260, USA.
Paul E Floreancig

Funding

University of Pittsburgh Center for Chemical DiversityP50GM067082 · NIGMS · UNIVERSITY OF PITTSBURGH AT PITTSBURGH · PI WIPF, PETER · 2002 to 2012
$18.6M
NIGMS NIH HHS P50-GM06082NIGMS NIH HHS P50 GM067082
6 · The paper itself

Abstract

Complexity from simplicity: polycyclic ethers are synthesized by cascade reactions involving the use of epoxides as electrophilic traps in the transposition of allylic alcohols. Stereogenic centers are created by functionalizing prochiral sites under thermodynamic control, and remote stereoinduction can be achieved through the use of ketones as conduits.

Indexed as

CatalysisEpoxy CompoundsEthers, CyclicMolecular StructurePolycyclic CompoundsPropanolsStereoisomerismallyl alcoholEpoxy CompoundsEthers, CyclicPolycyclic CompoundsPropanols

Identifiers

PMID23172717
PMCPMC3857712

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.