ArticleJournal of the American Chemical Society2012
Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.
Article in Journal of the American Chemical Society, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
21 citing papers in PubMed.
- Unlocking Catalyst Activation as a Critical Bottleneck in Cross-Coupling Reactions: Room-Temperature Couplings of Weak Nucleophiles Enabled by [Pd(1-MeNAP)TFA]Angewandte Chemie (International ed. in English) · 2026Article
- Aromaticity Tuning in Biaryl Monophosphines and Their Derivatives.Molecules (Basel, Switzerland) · 2025Article
- Aryl halide cross-coupling via formate-mediated transfer hydrogenation.Nature chemistry · 2025Article
- Unveiling the Latent Reactivity of Cp* Ligands (CInorganic chemistry · 2023Article
- Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification.Angewandte Chemie (International ed. in English) · 2023Article
- Important Role of NH-Carbazole in Aryl Amination Reactions Catalyzed by 2-Aminobiphenyl Palladacycles.ACS catalysis · 2023Article
- Dearomative logic in natural product total synthesis.Natural product reports · 2022Review
- Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation.The Journal of organic chemistry · 2019Article
- Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Bases.ACS catalysis · 2019Article
- Base-Promoted, Remote C-H Activation at a Cationic (ηJournal of the American Chemical Society · 2019Article
- Breaking the Base Barrier: An Electron-Deficient Palladium Catalyst Enables the Use of a Common Soluble Base in C-N Coupling.Journal of the American Chemical Society · 2018Article
- DirectJournal of the American Chemical Society · 2017Article
- Palladium-Mediated Arylation of Lysine in Unprotected Peptides.Angewandte Chemie (International ed. in English) · 2017Article
- The Evolution of PdAccounts of chemical research · 2016Article
- Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination.Journal of the American Chemical Society · 2016Article
- A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides.Journal of the American Chemical Society · 2015Article
- In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides.Organometallics · 2015Article
- Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Journal of the American Chemical Society · 2014Article
- Structure and Reactivity of [(L•Pd)Inorganica chimica acta · 2014Article
- Pd-catalyzed nucleophilic fluorination of aryl bromides.Journal of the American Chemical Society · 2014Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
A series of monoligated L·Pd(II)(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd(II)-mediated insertion of an aryl group into an unactivated arene.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.