ArticleInorganic chemistry2012
Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent.
Article in Inorganic chemistry, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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28 citing papers in PubMed.
- Controlling outer-sphere solvent reorganization energy to turn on or off the function of artificial metalloenzymes.Nature communications · 2025Article
- Effects of Additional Mesopores and the Surface Modification of the Y-Type Zeolite on the Alkane Oxidation Activity of Iron Complex-Encapsulated Catalysts.Molecules (Basel, Switzerland) · 2025Article
- Appended Lewis Acids Enable Dioxygen Reactivity and Catalytic Oxidations with Ni(II).Journal of the American Chemical Society · 2024Article
- Fenton-like Chemistry by a Copper(I) Complex and HJournal of the American Chemical Society · 2023Article
- Cu-promoted intramolecular hydroxylation of CH bonds using directing groups with varying denticity.Journal of inorganic biochemistry · 2021Article
- De Novo Design of a Self-Assembled Artificial Copper Peptide that Activates and Reduces Peroxide.ACS catalysis · 2021Article
- Article
- Amine-rich quartz nanoparticles for Cu(II) chelation and their application as an efficient catalyst for oxidative degradation of Rhodamine B dye.Environmental science and pollution research international · 2021Article
- Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase.Inorganic chemistry · 2020Article
- Directed Hydroxylation of spInorganic chemistry · 2019Article
- Mechanistic Dichotomy in Proton-Coupled Electron-Transfer Reactions of Phenols with a Copper Superoxide Complex.Journal of the American Chemical Society · 2019Article
- Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function.Chemical reviews · 2018Review
- Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes.Journal of the American Chemical Society · 2018Article
- Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes.Chemical communications (Cambridge, England) · 2018Article
- Peroxide Activation Regulated by Hydrogen Bonds within Artificial Cu Proteins.Journal of the American Chemical Society · 2017Article
- Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of spThe Journal of organic chemistry · 2017Article
- Formally Copper(III)-Alkylperoxo Complexes as Models of Possible Intermediates in Monooxygenase Enzymes.Journal of the American Chemical Society · 2017Article
- Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.Chemical reviews · 2017Review
- Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms.Israel journal of chemistry · 2016Article
- Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation.Journal of the American Chemical Society · 2016Article
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5 authors.
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Abstract
At -90 °C in acetone, a stable hydroperoxo complex [(BA)Cu(II)OOH](+) (2) (BA, a tetradentate N(4) ligand possessing a pendant -N(H)CH(2)C(6)H(5) group) is generated by reacting [(BA)Cu(II)(CH(3)COCH(3))](2+) with only 1 equiv of H(2)O(2)/Et(3)N. The exceptional stability of 2 is ascribed to internal H-bonding. Species 2 is also generated in a manner not previously known in copper chemistry, by adding 1.5 equiv of H(2)O(2) (no base) to the cuprous complex [(BA)Cu(I)](+). The broad implications for this finding are discussed. Species 2 slowly converts to a μ-1,2-peroxodicopper(II) analogue (3) characterized by UV-vis and resonance Raman spectroscopies. Unlike a close analogue not possessing internal H-bonding, 2 affords no oxidative reactivity with internal or external substrates. However, 2 can be protonated to release H(2)O(2), but only with HClO(4), while 1 equiv Et(3)N restores 2.
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