ArticleScientific reports2012
Entropy-driven liquid-liquid separation in supercooled water.
Article in Scientific reports, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 43 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
43 citing papers in PubMed.
- A Golden-Ratio Ladder and a Delocalisation-Saturated Participation Bridge for the Hydrogen-Bond Network of Liquid Water.Molecules (Basel, Switzerland) · 2026Article
- Machine learning evaluation of structural descriptors for supercooled water.Communications chemistry · 2026Article
- Universal Supercritical Thermodynamics for Black Holes.Research (Washington, D.C.) · 2026Article
- Liquid-Liquid Phase Separation in Hereditary Hearing Loss.Neuroscience bulletin · 2025Review
- Combined isochoric processes of freezing and supercooling.NPJ science of food · 2025Article
- Structural Origin of Dynamic Heterogeneity in Supercooled Liquids.The journal of physical chemistry. B · 2025Review
- Nuclear quantum effects on glassy water under pressure: Vitrification and pressure-induced transformations.The Journal of chemical physics · 2024Article
- Water Potential from Adaptive Force Matching for Ice and Liquid with Revised Dispersion Predicts Supercooled Liquid Anomalies in Good Agreement with Two Independent Experimental Fits.The journal of physical chemistry. B · 2024Article
- Calibrating TDDFT Calculations of the X-ray Emission Spectrum of Liquid Water: The Effects of Hartree-Fock Exchange.Journal of chemical theory and computation · 2023Article
- Anisotropy in spinodal-like dynamics of unknown water at ice V-water interface.Scientific reports · 2023Article
- Approach to hyperuniformity in a metallic glass-forming material exhibiting a fragile to strong glass transition.The European physical journal. E, Soft matter · 2023Article
- Liquid-liquid phase separation in supercooled water from ultrafast heating of low-density amorphous ice.Nature communications · 2023Article
- Correlated Fluctuations of Structural Indicators Close to the Liquid-Liquid Transition in Supercooled Water.The journal of physical chemistry. B · 2023Article
- Limiting Conductivities of Strong Acids and Bases in DThe journal of physical chemistry. B · 2022Article
- Article
- Evidence of a liquid-liquid phase transition in H[Formula: see text]O and D[Formula: see text]O from path-integral molecular dynamics simulations.Scientific reports · 2022Article
- From Critical Point to Critical Point: The Two-States Model Describes Liquid Water Self-Diffusion from 623 to 126 K.Molecules (Basel, Switzerland) · 2021Article
- Structural relaxation and crystallization in supercooled water from 170 to 260 K.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
- On the existence of soliton-like collective modes in liquid water at the viscoelastic crossover.Scientific reports · 2021Article
- The anomalies and criticality of liquid water.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Twenty years ago Poole et al. suggested that the anomalous properties of supercooled water may be caused by a critical point that terminates a line of liquid-liquid separation of lower-density and higher-density water. Here we present a thermodynamic model based on this hypothesis, which describes all available experimental data for supercooled water with better quality and fewer adjustable parameters than any other model. Liquid water at low temperatures is viewed as an 'athermal solution' of two molecular structures with different entropies and densities. Alternatively to popular models for water, in which liquid-liquid separation is driven by energy, the phase separation in the athermal two-state water is driven by entropy upon increasing the pressure, while the critical temperature is defined by the 'reaction' equilibrium constant. The model predicts the location of density maxima at the locus of a near-constant fraction of the lower-density structure.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.