ArticleThe journal of physical chemistry. B2013
Differential hydration of tricyanomethanide observed by time resolved vibrational spectroscopy.
Article in The journal of physical chemistry. B, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
6 citing papers in PubMed, 27 citations in OpenAlex.
- Lithium ion Speciation in Cyclic Solvents: Impact of Anion Charge Delocalization and Solvent Polarizability.The journal of physical chemistry. B · 2024Article
- Non-linear infrared spectroscopy of the water bending mode: direct experimental evidence of hydration shell reorganization?Physical chemistry chemical physics : PCCP · 2014Article
- Quantum process tomography quantifies coherence transfer dynamics in vibrational exciton.The journal of physical chemistry. B · 2013Article
- Vibrational dynamics of a non-degenerate ultrafast rotor: the (C12,C13)-oxalate ion.The Journal of chemical physics · 2013Article
- An ion's perspective on the molecular motions of nanoconfined water: a two-dimensional infrared spectroscopy study.The journal of physical chemistry. B · 2013Article
- Quantum Beats and Coherence Decay in Degenerate States Split by Solvation.The journal of physical chemistry letters · 2013Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors at 2 institutions in 1 country.
Funding
Abstract
The degenerate transition corresponding to asymmetric stretches of the D(3h) tricyanomethanide anion, C(CN)(3)(-), in aqueous solution was investigated by linear FTIR spectroscopy, femtosecond pump–probe spectroscopy, and 2D IR spectroscopy. Time resolved vibrational spectroscopy shows that water induces vibrational energy transfer between the degenerate asymmetric stretch modes of tricyanomethanide. The frequency–frequency correlation function and the vibrational energy transfer show two significantly different ultrafast time scales. The system is modeled with molecular dynamics simulations and ab initio calculations. A new model for theoretically describing the vibrational dynamics of a degenerate transition is presented. Microscopic models, where water interacts axially and radially with the ion, are suggested for the transition dipole reorientation mechanism.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.