Evidence map›Paper›PMID 22873832›Full record

ArticleOrganic letters2012

Oxidative condensations to form benzimidazole-substituted potassium organotrifluoroborates.

Gary A Molander, Kehinde Ajayi

Abstract read
In one paragraph

Article in Organic letters, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
3.3field-weighted citation impact, top 8% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 49 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

Gary A MolanderRoy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, United States. gmolandr@sas.upenn.edu
Kehinde Ajayi
University of Pennsylvania · US

Funding

Organotrifluoroborates in Selective Organic SynthesisR01GM035249 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI MOLANDER, GARY A · 1985 to 2013
$4.0M
Novel Organoboron Chemistry Utilizing TetrahydroxydiboraneR01GM081376 · NIGMS · UNIVERSITY OF PENNSYLVANIA · PI MOLANDER, GARY A · 2007 to 2015
$2.6M
Agilent 5973 GC/MS SystemS10RR016640 · NCRR · UNIVERSITY OF PENNSYLVANIA · PI MOLANDER, GARY A · 2002 to 2002
$105k
NCRR NIH HHS S10 RR016640NIGMS NIH HHS R01 GM035249NIGMS NIH HHS R01 GM081376
6 · The paper itself

Abstract

A library of benzimidazole-substituted potassium organotrifluoroborates was prepared via the condensation of various potassium formyl-substituted aryl- and heteroaryltrifluoroborates with aromatic 1,2-diamines under oxidative conditions. The efficient Suzuki-Miyaura cross-coupling of products thus formed to various aryl and heteroaryl bromides was achieved in good yields. The method allows the facile preparation of benzimidazole-containing triaromatic products in two steps from simple potassium formyl substituted aryl- or heteroaryltrifluoroborates.

Indexed as

BenzimidazolesBoratesCatalysisCombinatorial Chemistry TechniquesDiaminesHydrocarbons, FluorinatedMolecular StructureOxidation-ReductionPotassiumBenzimidazolesBoratesDiaminesHydrocarbons, FluorinatedPotassium

Identifiers

PMID22873832
PMCPMC3428750
OpenAlexW2034868060

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.