ReviewJournal of the Royal Society, Interface2012
Nano-sized manganese oxides as biomimetic catalysts for water oxidation in artificial photosynthesis: a review.
Review in Journal of the Royal Society, Interface, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Honoring two stalwarts of photosynthesis research: Eva-Mari Aro and Govindjee.Photosynthesis research · 2023Article
- Toward Escherichia coli bacteria machine for water oxidation.Photosynthesis research · 2018Article
- Thermodynamics of manganese oxides: Sodium, potassium, and calcium birnessite and cryptomelane.Proceedings of the National Academy of Sciences of the United States of America · 2017Article
- Nanostructured manganese oxide on silica aerogel: a new catalyst toward water oxidation.Photosynthesis research · 2016Article
- Effects of Subcutaneous Injection MnOIranian journal of medical sciences · 2016Article
- Manganese oxides supported on gold nanoparticles: new findings and current controversies for the role of gold.Photosynthesis research · 2015Article
- The effect of lanthanum(III) and cerium(III) ions between layers of manganese oxide on water oxidation.Photosynthesis research · 2015Article
- An approach for catalyst design in artificial photosynthetic systems: focus on nanosized inorganic cores within proteins.Photosynthesis research · 2013Review
- Gold or silver deposited on layered manganese oxide: a functional model for the water-oxidizing complex in photosystem II.Photosynthesis research · 2013Article
- Imidazolium or guanidinium/layered manganese (III, IV) oxide hybrid as a promising structural model for the water-oxidizing complex of Photosystem II for artificial photosynthetic systems.Photosynthesis research · 2013Article
- Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation.Proceedings of the National Academy of Sciences of the United States of America · 2013Article
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
There has been a tremendous surge in research on the synthesis of various metal compounds aimed at simulating the water-oxidizing complex (WOC) of photosystem II (PSII). This is crucial because the water oxidation half reaction is overwhelmingly rate-limiting and needs high over-voltage (approx. 1 V), which results in low conversion efficiencies when working at current densities required for hydrogen production via water splitting. Particular attention has been given to the manganese compounds not only because manganese has been used by nature to oxidize water but also because manganese is cheap and environmentally friendly. The manganese-calcium cluster in PSII has a dimension of about approximately 0.5 nm. Thus, nano-sized manganese compounds might be good structural and functional models for the cluster. As in the nanometre-size of the synthetic models, most of the active sites are at the surface, these compounds could be more efficient catalysts than micrometre (or bigger) particles. In this paper, we focus on nano-sized manganese oxides as functional and structural models of the WOC of PSII for hydrogen production via water splitting and review nano-sized manganese oxides used in water oxidation by some research groups.
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