ArticleChemical communications (Cambridge, England)2013
The efficient desymmetrization of glycerol using scaffolding catalysis.
Article in Chemical communications (Cambridge, England), 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Copper-Catalyzed Asymmetric Sulfonylative Desymmetrization of Glycerol.Molecules (Basel, Switzerland) · 2022Article
- Dynamic kinetic resolution of transient hemiketals: a strategy for the desymmetrisation of prochiral oxetanols.Chemical science · 2022Article
- Broad-spectrum kinetic resolution of alcohols enabled by Cu-H-catalysed dehydrogenative coupling with hydrosilanes.Nature communications · 2017Article
- Synthesis of 5'-O-DMT-2'-O-TBS Mononucleosides Using an Organic Catalyst.Current protocols in nucleic acid chemistry · 2014Review
- Distal-selective hydroformylation using scaffolding catalysis.Journal of the American Chemical Society · 2014Article
- Practical silyl protection of ribonucleosides.Organic letters · 2013Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
Glycerol is an ideal building block for the synthesis of complex molecules, because it is inexpensive and highly functionalized. We report the desymmetrization of glycerol through silyl transfer, using a chiral organic catalyst in high yield and enantioselectivity.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.