ArticleThe Journal of organic chemistry2012
Aromatic cations from oxidative carbon-hydrogen bond cleavage in bimolecular carbon-carbon bond forming reactions.
Article in The Journal of organic chemistry, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Development and Mechanistic Studies of Oxidative Prins-Semipinacol Cyclization Reactions.Organic letters · 2026Article
- The single Fe atoms and DDQ catalyst system for the aerobic dehydrogenation of dihydropyridines and dihydroquinazolinones.Scientific reports · 2025Article
- Copper-catalyzed oxidative cross-dehydrogenative coupling of 2H-chromenes and terminal alkynes.Organic & biomolecular chemistry · 2018Article
- Remodeling of fumagillol: discovery of an oxygen-directed oxidative Mannich reaction.Organic letters · 2014Article
- Bimolecular Coupling Reactions through Oxidatively Generated Aromatic Cations: Scope and Stereocontrol.Tetrahedron · 2013Article
- Kinetic resolution in asymmetric epoxidation using iminium salt catalysis.The Journal of organic chemistry · 2013Article
- Cyclopropane compatibility with oxidative carbocation formation: total synthesis of clavosolide A.Organic letters · 2012Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Chromenes and isochromenes react quickly with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) to form persistent aromatic oxocarbenium ions through oxidative carbon-hydrogen cleavage. This process is tolerant of electron-donating and electron-withdrawing groups on the benzene ring and additional substitution on the pyran ring. A variety of nucleophiles can be added to these cations to generate a diverse set of structures.
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Registered trials
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