ArticleThe Journal of organic chemistry2013
Crotylboron-based synthesis of the polypropionate units of chaxamycins A/D, salinisporamycin, and rifamycin S.
Article in The Journal of organic chemistry, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Salinirifamycins A-E: Rifamycin S Derivatives from the Brazilian Marine ActinomyceteJournal of natural products · 2026Article
- Epoxide-Based Synthetic Approaches toward Polypropionates and Related Bioactive Natural Products.International journal of molecular sciences · 2023Review
- (Chemical science · 2019Article
- Stereoselective one-pot synthesis of polypropionates.Nature communications · 2017Article
- Article
- Article
- Enantioselective synthesis of (Z)- and (E)-2-methyl-1,5-anti-pentenediols via an allene hydroboration-double-allylboration reaction sequence.Journal of the American Chemical Society · 2013Article
- Enantioselective synthesis of (E)-δ-silyl-anti-homoallylic alcohols via an enantiodivergent hydroboration-crotylboration reaction of a racemic allenylsilane.Organic letters · 2013Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Syntheses of the C(15)-C(27) fragments of chaxamycins A/D, rifamycin S, and the C(12)-C(24) fragment of salinisporamycin have been accomplished in 10 steps from commercially available starting materials. Three crotylboron reagents were utilized to construct the seven contiguous stereocenters in these fragments with excellent stereoselectivity.
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Registered trials
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