ArticleOrganic letters2012
Total synthesis of (±)-7-epi-nemorosone.
Article in Organic letters, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Total Synthesis of Hypersampsone M.Journal of the American Chemical Society · 2024Article
- Regiodivergent biosynthesis of bridged bicyclononanes.Nature communications · 2024Article
- Dearomative logic in natural product total synthesis.Natural product reports · 2022Review
- An invocation for computational evaluation of isomerization transforms: cationic skeletal reorganizations as a case study.Natural product reports · 2021Review
- Synthesis and Multiplexed Activity Profiling of Synthetic Acylphloroglucinol Scaffolds.Angewandte Chemie (International ed. in English) · 2021Article
- Programmable meroterpene synthesis.Nature communications · 2020Article
- Regiodivergent Photocyclization of Dearomatized Acylphloroglucinols: Asymmetric Syntheses of (-)-Nemorosone and (-)-6-Journal of the American Chemical Society · 2019Article
- Asymmetric Dearomatization/Cyclization Enables Access to Polycyclic Chemotypes.European journal of organic chemistry · 2016Article
- Identification of a novel polyprenylated acylphloroglucinol‑derived SIRT1 inhibitor with cancer‑specific anti-proliferative and invasion-suppressing activities.International journal of oncology · 2014Article
- Rapid synthesis of polyprenylated acylphloroglucinol analogs via dearomative conjunctive allylic annulation.Journal of the American Chemical Society · 2014Article
- Asymmetric, stereodivergent synthesis of (-)-clusianone utilizing a biomimetic cationic cyclization.Angewandte Chemie (International ed. in English) · 2014Article
- Evolution of an oxidative dearomatization enabled total synthesis of vinigrol.Organic & biomolecular chemistry · 2014Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
A concise total synthesis of (±)-7-epi-nemorosone is reported. Our synthetic approach establishes a viable route to polycyclic polyprenylated acylphloroglucinol natural products (PPAP's) bearing a C-7 endo prenyl side chain. Key steps include retro-aldol-vinyl cerium addition to a hydroxy adamantane core scaffold and palladium-mediated deoxygenation.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.