ArticleNature communications2012
Precise hierarchical self-assembly of multicompartment micelles.
Article in Nature communications, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 49 papers.
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Who cites it
49 citing papers in PubMed.
- Photoresponsive Reversible Assembly of Helical Poly(isocyanide)s.ACS polymers Au · 2026Article
- The Role of Chemistry Across Disciplines From Humanities to Life Sciences in Understanding Complexity and Emergence.Angewandte Chemie (International ed. in English) · 2026Review
- Biomimetic peptide self-assembly: interfacing with biomacromolecules to regulate cellular signaling.Experimental & molecular medicine · 2026Review
- Kinetically controlled hetero-fusion is a systems-level behaviour of polymer nanoparticle populations.Nature communications · 2025Article
- Asymmetric Microgels with Tunable Morphologies by Assembly-Guided Polymerization of Liquid Crystalline Monomers.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Stereospecific supramolecular polymerization of nanoclusters into ultra-long helical chains and enantiomer separation.Nature communications · 2024Article
- Nanoarchitectonics for synergistic activity of multimetallic nanohybrids as a possible approach for antimicrobial resistance (AMR).Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2024Review
- Block Sequence Effects on the Self-Assembly Behaviors of Polypeptide-Based Penta-Block Copolymer Hydrogels.ACS applied materials & interfaces · 2024Article
- Nonequilibrium Colloids: Temperature-Induced Bouquet Formation of Flower-like Micelles as a Time-Domain-Shifting Macromolecular Heat Alert.ACS applied materials & interfaces · 2023Review
- Dynamic Light Scattering Based Microrheology of End-Functionalised Triblock Copolymer Solutions.Polymers · 2023Article
- Article
- Catalytically Active Multicompartment Micelles.JACS Au · 2022Article
- Nano-to-micro spatiotemporal imaging of magnetic skyrmion's life cycle.Science advances · 2021Article
- Mikto-Arm Stars as Soft-Patchy Particles: From Building Blocks to Mesoscopic Structures.Polymers · 2021Article
- Hierarchical supramolecular assembly of a single peptoid polymer into a planar nanobrush with two distinct molecular packing motifs.Proceedings of the National Academy of Sciences of the United States of America · 2020Article
- Straightforward preparation of supramolecular Janus nanorods by hydrogen bonding of end-functionalized polymers.Nature communications · 2020Article
- Supracolloidal Self-Assembly of Divalent Janus 3D DNA Origami via Programmable Multivalent Host/Guest Interactions.Angewandte Chemie (International ed. in English) · 2020Article
- Synthesis of ABChemical science · 2020Article
- Hollow Bio-derived Polymer Nanospheres with Ordered Mesopores for Sodium-Ion Battery.Nano-micro letters · 2020Article
- The effect of solvent quality on pathway-dependent solution-state self-assembly of an amphiphilic diblock copolymer.Journal of applied physics · 2020Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Hierarchical self-assembly offers elegant and energy-efficient bottom-up strategies for the structuring of complex materials. For block copolymers, the last decade witnessed great progress in diversifying the structural complexity of solution-based assemblies into multicompartment micelles. However, a general understanding of what governs multicompartment micelle morphologies and polydispersity, and how to manipulate their hierarchical superstructures using straightforward concepts and readily accessible polymers remains unreached. Here we demonstrate how to create homogeneous multicompartment micelles with unprecedented structural control via the intermediate pre-assembly of subunits. This directed self-assembly leads to a step-wise reduction of the degree of conformational freedom and dynamics and avoids undesirable kinetic obstacles during the structure build-up. It yields a general concept for homogeneous populations of well-defined multicompartment micelles with precisely tunable patchiness, while using simple linear ABC triblock terpolymers. We further demonstrate control over the hierarchical step-growth polymerization of multicompartment micelles into micron-scale segmented supracolloidal polymers as an example of programmable mesoscale colloidal hierarchies via well-defined patchy nanoobjects.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.