ArticleOrganic letters2012
Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins.
Article in Organic letters, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Copper-catalyzed oxidative amination and allylic amination of alkenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2013Article
- A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Tetrahedron · 2013Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Tandem reaction sequences that selectively convert multiple C-H bonds of abundant hydrocarbon feedstocks to functionalized materials enable rapid buildup of molecular complexity in an economical way. A tandem C-H amination/vinylic C-H arylation reaction sequence is described under Pd(II)/sulfoxide-catalysis that furnishes a wide range of α- and β-homophenylalanine precursors from commodity α-olefins and readily available aryl boronic acids. General routes to enantiopure amino acid esters and densely functionalized homophenylalanine derivatives are demonstrated.
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Registered trials
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