Evidence map›Paper›PMID 22349519›Full record

ArticleOrganic & biomolecular chemistry2012

Expedient synthesis of α-substituted fluoroethenes.

Samir K Mandal, Arun K Ghosh, Rakesh Kumar, Barbara Zajc

Abstract read
In one paragraph

Article in Organic & biomolecular chemistry, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Copper-Catalyzed Regioselective Synthesis of (Molecules (Basel, Switzerland) · 2019
    Article
  3. Article
  4. Article
  5. Article
  6. Article
  7. Stereoselective synthesis of conjugated fluoro enynes.The Journal of organic chemistry · 2012
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Samir K MandalDepartment of Chemistry, The City College and The City University of New York, New York, New York 10031-9198, USA.
Arun K Ghosh
Rakesh Kumar
Barbara Zajc

Funding

TNC FUNCTION IN APOPTOTIC ANTIGEN DRIVEN AUTOIMMUNITYG12RR003060 · NCRR · CITY COLLEGE OF NEW YORK · PI WALLMAN, JOSHUA · 1985 to 2011
$26.1M
VOLTAGE GATING OF ION CHANNELS--SIMULATIONS AND AB INITIO CALCULATIONSS06GM008168 · NIGMS · CITY COLLEGE OF NEW YORK · PI VENKATESH, TADMIRI RANGACHAR · 1989 to 2010
$17.6M
Cellular/Molecular Basis of Development: Research CenterG12MD007603 · NIMHD · CITY COLLEGE OF NEW YORK · PI PEZZANO, MARK · 2012 to 2017
$11.5M
NCRR NIH HHS 5G12 RR03060NCRR NIH HHS G12 RR003060NIGMS NIH HHS S06 GM008168NIMHD NIH HHS G12 MD007603
6 · The paper itself

Abstract

A mild and efficient synthesis of 1-aryl-1-fluoroethenes from benzothiazolyl (aryl)fluoromethyl sulfones and paraformaldehyde, under DBU- or Cs(2)CO(3)-mediated conditions at room temperature, is described. A comparable diethyl fluoro(naphthalen-2-yl)methylphosphonate reagent does not react with paraformaldehyde under these mild conditions. The utility of the methodology for synthesis of terminal α-fluoroalkenes bearing electron-withdrawing functionalities is also shown.

Indexed as

Chemistry Techniques, SyntheticEthylenesFluorineFormaldehydeHalogenationPolymersSulfonesethyleneEthylenesFluorineFormaldehydeparaformPolymersSulfones

Identifiers

PMID22349519
PMCPMC3723398

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.