ArticleJournal of the American Society for Mass Spectrometry2012
Dipolar DC collisional activation in a “stretched” 3-D ion trap: the effect of higher order fields on rf-heating.
Article in Journal of the American Society for Mass Spectrometry, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed, 37 citations in OpenAlex.
- Proton transfer reagent cations for ion-ion charge state manipulation of high mass negatively-charged analytes in an electrodynamic ion trap.The Analyst · 2026Article
- An Analytical Evaluation of Tools for Lipid Isomer Differentiation in Imaging Mass Spectrometry.International journal of mass spectrometry · 2024Article
- Adaptation and Operation of a Quadrupole/Time-of-Flight Tandem Mass Spectrometer for High Mass Ion/Ion Reaction Studies.International journal of mass spectrometry · 2022Article
- Digital ion trap mass analysis of high mass protein complexes using IR activation coupled with ion/ion reactions.International journal of mass spectrometry · 2020Article
- Ion/ion Charge Inversion/Attachment in Conjunction with Dipolar DC Collisional Activation as a Selective Screen for Sulfo- and Phosphopeptides.International journal of mass spectrometry · 2019Article
- Dipolar DC induced collisional activation of non-dissociated electron-transfer products.Journal of mass spectrometry : JMS · 2019Article
- Dual-Polarity Ion Trap Mass Spectrometry: Dynamic Monitoring and Controlling Gas-phase Ion-Ion Reactions.Journal of the American Society for Mass Spectrometry · 2017Article
- Multigenerational Broadband Collision-Induced Dissociation of Precursor Ions in a Linear Quadrupole Ion Trap.Journal of the American Society for Mass Spectrometry · 2016Article
- Characteristics of Ion Activation and Collision Induced Dissociation Using Digital Ion Trap Technology.Journal of the American Society for Mass Spectrometry · 2016Article
- Selective Covalent Chemistry via Gas-Phase Ion/ion Reactions: An Exploration of the Energy Surfaces Associated with N-Hydroxysuccinimide Ester Reagents and Primary Amines and Guanidine Groups.Journal of the American Society for Mass Spectrometry · 2016Article
- Miniature and Fieldable Mass Spectrometers: Recent Advances.Analytical chemistry · 2016Review
- Simulation of electric potentials and ion motion in planar electrode structures for lossless ion manipulations (SLIM).Journal of the American Society for Mass Spectrometry · 2014Article
- Ion sponge: a 3-dimentional array of quadrupole ion traps for trapping and mass-selectively processing ions in gas phase.Analytical chemistry · 2014Article
- Resonance activation and collision-induced-dissociation of ions using rectangular wave dipolar potentials in a digital ion trap mass spectrometer.Journal of the American Society for Mass Spectrometry · 2014Article
- Space charge induced nonlinear effects in quadrupole ion traps.Journal of the American Society for Mass Spectrometry · 2014Article
- Can the effective potential of a linear quadrupole be extended to values of the Mathieu parameter q up to 0.90?Journal of the American Society for Mass Spectrometry · 2013Article
- Trapping mode dipolar DC collisional activation in the RF-only ion guide of a linear ion trap/time-of-flight instrument for gaseous bio-ion declustering.Journal of mass spectrometry : JMS · 2013Article
- Boundary-activated dissociation in a low pressure linear quadrupole ion trap in the presence of nonlinear DC fields.Journal of the American Society for Mass Spectrometry · 2012Article
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Applying dipolar DC (DDC) to the end-cap electrodes of a 3-D ion trap operated with a bath gas at roughly 1 mTorr gives rise to ‘rf-heating’ and can result in collision-induced dissociation (CID). This approach to ion trap CID differs from the conventional single-frequency resonance excitation approach in that it does not rely on tuning a supplementary frequency to coincide with the fundamental secular frequeny of the precursor ion of interest. Simulations using the program ITSIM 5.0 indicate that application of DDC physically displaces ions solely in the axial (inter end-cap) dimension whereupon ion acceleration occurs via power absorption from the drive rf. Experimental data shows that the degree of rf-heating in a stretched 3-D ion trap is not dependent solely on the ratio of the dipolar DC voltage/radio frequency (rf) amplitude, as a model based on a pure quadrupole field suggests. Rather, ion temperatures are shown to increase as the absolute values of the dipolar DC and rf amplitude both decrease. Simulations indicate that the presence of higher order multi-pole fields underlies this unexpected behavior. These findings have important implications for the use of DDC as a broad-band activation approach in multi-pole traps.
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