ArticleJournal of porphyrins and phthalocyanines2011
Synthetic protocols for the nitration of corroles.
Article in Journal of porphyrins and phthalocyanines, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Functionalization of β-Alkylcorrole Using Ag(I) Salts.Inorganic chemistry · 2026Article
- Benzothiazole Functionalized Corrole Based Donor-Acceptor Dyads: Synthesis, Photophysical Studies, and Investigating the Role of Benzothiazole in Light Induced Events.Chemistry, an Asian journal · 2026Article
- Corrole and nucleophilic aromatic substitution are not incompatible: a novel route to 2,3-difunctionalized copper corrolates.Organic & biomolecular chemistry · 2015Article
- 3-NO2-5,10,15-triarylcorrolato-Cu as a versatile platform for synthesis of novel 3-functionalized corrole derivatives.Organic & biomolecular chemistry · 2014Article
- Copper β-trinitrocorrolates.Journal of porphyrins and phthalocyanines · 2013Article
- β-Nitro-5,10,15-tritolylcorroles.Inorganic chemistry · 2012Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The modification of peripheral positions of corroles by introduction of nitro groups is an important functionalization of this macrocycle. The nitro substituent strongly influences the corrole behavior leading to the preparation of macrocycles with different properties, which can be of interest for their exploitation as catalysts, sensing layers in chemical sensors or in the field of supramolecular chemistry. In the last few years we have developed different routes for the β-nitration of the corrole ring, and we report here novel synthetic protocols which can allow the formation of tri- and tetranitro derivatives, as demonstrated by X-ray analysis. In all of the methodologies used, the presence of isocorrole species as reaction intermediates was established, which regenerated the corresponding corrole by metal insertion.
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Registered trials
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