ReviewMolecules (Basel, Switzerland)2012
Recent applications of the (TMS)3SiH radical-based reagent.
Review in Molecules (Basel, Switzerland), 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
20 citing papers in PubMed.
- Radical Borylation of Alkyl Bromides by Photoinduced Halogen-Atom Transfer.Angewandte Chemie (International ed. in English) · 2025Article
- Radical Reactions in Organic Synthesis: Exploring in-, on-, and with-Water Methods.Molecules (Basel, Switzerland) · 2024Review
- Recent Advances in Monocomponent Visible Light Photoinitiating Systems Based on Sulfonium Salts.Polymers · 2023Review
- Metal-free reductive desulfurization of C-spChemical science · 2023Article
- 1,5-Hydrogen Atom Transfer/Surzur-Tanner Rearrangement: A Radical Cascade Approach for the Synthesis of 1,6-Dioxaspiro[4.5]decane and 6,8-Dioxabicyclo[3.2.1]octane Scaffolds in Carbohydrate Systems.The Journal of organic chemistry · 2021Article
- Hydrofluoromethylation of alkenes with fluoroiodomethane and beyond.Chemical science · 2021Article
- Free-radical cyclization approach to polyheterocycles containing pyrrole and pyridine rings.Beilstein journal of organic chemistry · 2021Article
- Moving Towards a Finer Way of Light-Cured Resin-Based Restorative Dental Materials: Recent Advances in Photoinitiating Systems Based on Iodonium Salts.Materials (Basel, Switzerland) · 2020Review
- Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids.Angewandte Chemie (International ed. in English) · 2020Article
- A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of α-Chloro Carbonyls with Aryl Halides.Angewandte Chemie (International ed. in English) · 2019Article
- Visible-light-mediated Minisci C-H alkylation of heteroarenes with unactivated alkyl halides using OChemical science · 2019Article
- Metallaphotoredox-Catalyzed Cross-Electrophile CJournal of the American Chemical Society · 2018Article
- Metallaphotoredox Difluoromethylation of Aryl Bromides.Angewandte Chemie (International ed. in English) · 2018Article
- Silyl-mediated photoredox-catalyzed Giese reaction: addition of non-activated alkyl bromides.Chemical science · 2018Article
- An expeditious and efficient bromomethylation of thiols: enabling bromomethyl sulfides as useful building blocks.RSC advances · 2018Article
- Silane-Acrylate Chemistry for Regulating Network Formation in Radical Photopolymerization.Macromolecules · 2017Article
- Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling.Journal of the American Chemical Society · 2016Article
- Development of methacrylate/silorane hybrid monomer system: Relationship between photopolymerization behavior and dynamic mechanical properties.Journal of biomedical materials research. Part B, Applied biomaterials · 2016Article
- Tris(trimethylsilyl)silane as a co-initiator for dental adhesive: Photo-polymerization kinetics and dynamic mechanical property.Dental materials : official publication of the Academy of Dental Materials · 2016Article
- Initiators Based on Benzaldoximes: Bimolecular and Covalently Bound Systems.Macromolecules · 2012Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
This review article focuses on the recent applications of tris(trimethylsilyl)silane as a radical-based reagent in organic chemistry. Numerous examples of the successful use of (TMS)(3)SiH in radical reductions, hydrosilylation and consecutive radical reactions are given. The use of (TMS)(3)SiH allows reactions to be carried out under mild conditions with excellent yields of products and remarkable chemo-, regio-, and stereoselectivity. The strategic role of (TMS)(3)SiH in polymerization is underlined with emphasis on the photo-induced radical polymerization of olefins and photo-promoted cationic polymerization of epoxides.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.