ReviewComputer methods in biomechanics and biomedical engineering2013
Spatial variation of permittivity of an electrolyte solution in contact with a charged metal surface: a mini review.
Review in Computer methods in biomechanics and biomedical engineering, 2013. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Ionic Associations and Hydration in the Electrical Double Layer of Water-in-Salt Electrolytes.ACS applied materials & interfaces · 2025Article
- Dynamic Response of Ion Transport in Nanoconfined Electrolytes.Nano letters · 2023Article
- Opto-Electrostatic Determination of Nucleic Acid Double-Helix Dimensions and the Structure of the Molecule-Solvent Interface.Macromolecules · 2022Article
- Electric Double Layer and Orientational Ordering of Water Dipoles in Narrow Channels within a Modified Langevin Poisson-Boltzmann Model.Entropy (Basel, Switzerland) · 2020Article
- Interaction between dipolar lipid headgroups and charged nanoparticles mediated by water dipoles and ions.International journal of molecular sciences · 2013Article
- Monovalent ions and water dipoles in contact with dipolar zwitterionic lipid headgroups-theory and MD simulations.International journal of molecular sciences · 2013Article
- Effects of non-Newtonian power law rheology on mass transport of a neutral solute for electro-osmotic flow in a porous microtube.Biomicrofluidics · 2013Article
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Authors and funding
4 authors.
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Abstract
Contact between a charged metal surface and an electrolyte implies a particular ion distribution near the charged surface, i.e. the electrical double layer. In this mini review, different mean-field models of relative (effective) permittivity are described within a simple lattice model, where the orientational ordering of water dipoles in the saturation regime is taken into account. The Langevin-Poisson-Boltzmann (LPB) model of spatial variation of the relative permittivity for point-like ions is described and compared to a more general Langevin-Bikerman (LB) model of spatial variation of permittivity for finite-sized ions. The Bikerman model and the Poisson-Boltzmann model are derived as limiting cases. It is shown that near the charged surface, the relative permittivity decreases due to depletion of water molecules (volume-excluded effect) and orientational ordering of water dipoles (saturation effect). At the end, the LPB and LB models are generalised by also taking into account the cavity field.
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