ArticleJournal of the American Chemical Society2012
Preparation and properties of a monomeric high-spin Mn(V)-oxo complex.
Article in Journal of the American Chemical Society, 2012. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
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Who cites it
37 citing papers in PubMed.
- Bimetallic Chemistry by Design: Approaches to the Development of Multifunctional Ligands.Coordination chemistry reviews · 2026Article
- Activation of the Ground and Excited State of a Luminescent Osmium(VI) Dioxo Dicyano Complex with Lewis Acids.Journal of the American Chemical Society · 2026Article
- High-Spin Manganese(V) in an Active Center Analogue of the Oxygen-Evolving Complex.Journal of the American Chemical Society · 2025Article
- Nitrene-Transfer Chemistry to C-H and C═C Bonds Mediated by Triangular Coinage Metal Platforms Supported by Triply Bridging Pnictogen Elements Sb(III) and Bi(III).Organometallics · 2024Article
- Formation of a Reactive [Mn(III)-O-Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes.Angewandte Chemie (International ed. in English) · 2024Article
- Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(IV)-oxo adducts.Dalton transactions (Cambridge, England : 2003) · 2021Article
- Concerted proton-electron transfer reactions of manganese-hydroxo and manganese-oxo complexes.Chemical communications (Cambridge, England) · 2020Article
- Universal scaling relations for the rational design of molecular water oxidation catalysts with near-zero overpotential.Nature communications · 2019Article
- Regulating the Basicity of Metal-Oxido Complexes with a Single Hydrogen Bond and Its Effect on C-H Bond Cleavage.Journal of the American Chemical Society · 2019Article
- Dioxygen Activation with Molybdenum Complexes Bearing Amide-Functionalized Iminophenolate Ligands.Molecules (Basel, Switzerland) · 2019Article
- Manganese-Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand.Inorganic chemistry · 2018Article
- Hydrogen Bonds Dictate OJournal of the American Chemical Society · 2018Article
- Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex.Chemical science · 2018Article
- Involvement of high-valent manganese-oxo intermediates in oxidation reactions: realisation in nature, nano and molecular systems.Nano convergence · 2018Review
- Intramolecular C-H and C-F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC.Inorganic chemistry · 2017Article
- Synthetic control and empirical prediction of redox potentials for CoChemical science · 2017Article
- Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in FeAngewandte Chemie (International ed. in English) · 2017Article
- Oxygen activation by mononuclear Mn, Co, and Ni centers in biology and synthetic complexes.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2017Review
- Modulating the Primary and Secondary Coordination Spheres within a Series of CoInorganic chemistry · 2017Article
- Cobalt Kβ valence-to-core X-ray emission spectroscopy: a study of low-spin octahedral cobalt(iii) complexes.Dalton transactions (Cambridge, England : 2003) · 2016Article
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Abstract
Oxomanganese(V) species have been implicated in a variety of biological and synthetic processes, including their role as a key reactive center within the oxygen-evolving complex in photosynthesis. Nearly all mononuclear Mn(V)-oxo complexes have tetragonal symmetry, producing low-spin species. A new high-spin Mn(V)-oxo complex that was prepared from a well-characterized oxomanganese(III) complex having trigonal symmetry is now reported. Oxidation experiments with [FeCp(2)](+) were monitored with optical and electron paramagnetic resonance (EPR) spectroscopies and support a high-spin oxomanganese(V) complex formulation. The parallel-mode EPR spectrum has a distinctive S = 1 signal at g = 4.01 with a six-line hyperfine pattern having A(z) = 113 MHz. The presence of an oxo ligand was supported by resonance Raman spectroscopy, which revealed O-isotope-sensitive peaks at 737 and 754 cm(-1) assigned as a Fermi doublet centered at 746 cm(-1)(Δ(18)O = 31 cm(-1)). Mn Kβ X-ray emission spectra showed Kβ' and Kβ(1,3) bands at 6475.92 and 6490.50 eV, respectively, which are characteristic of a high-spin Mn(V) center.
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