ArticleAustralian journal of chemistry2011
Photocatalytic Water Oxidation Using Manganese Compounds Immobilized in Nafion Polymer Membranes.
Article in Australian journal of chemistry, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 25 citations in OpenAlex.
- The effect of lanthanum(III) and cerium(III) ions between layers of manganese oxide on water oxidation.Photosynthesis research · 2015Article
- Rate and mechanism of the photoreduction of birnessite (MnO2) nanosheets.Proceedings of the National Academy of Sciences of the United States of America · 2015Article
- Imidazolium or guanidinium/layered manganese (III, IV) oxide hybrid as a promising structural model for the water-oxidizing complex of Photosystem II for artificial photosynthetic systems.Photosynthesis research · 2013Article
- Gold or silver deposited on layered manganese oxide: a functional model for the water-oxidizing complex in photosystem II.Photosynthesis research · 2013Article
- Light-driven water oxidation for solar fuels.Coordination chemistry reviews · 2012Article
Corrections and comments
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Authors and funding
3 authors at 2 institutions in 1 country.
Funding
Abstract
Robust water oxidation catalysts using earth abundant metals are required as part of an overall scheme to convert sunlight into fuels. Here, we report the immobilization of [[Formula: see text]O(5)(terpy)(4)(H(2)O)(2)](ClO(4))(6) (terpy = 2,2';6',2″-terpyridine), [Mn(4)O(6)(tacn)(4)](ClO(4))(4) (tacn = 1,4,7-triazacyclononane), and manganese dioxide nanoparticles in Nafion on fluorine-doped tin oxide conducting glass electrodes. The electrodes are illuminated with white light in the presence of an applied potential and the resulting photocurrent is assigned to the oxidation of solvent water. Photodecomposition of the tetrameric complexes results in a material that is more active for light-driven electrooxidation of water. The reactivity, wavelength dependence, and stability of the compounds in Nafion under illumination are discussed.
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Registered trials
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