ArticleJournal of the American Chemical Society2011
Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides.
Article in Journal of the American Chemical Society, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 35 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
35 citing papers in PubMed.
- Unveiling the Latent Reactivity of Cp* Ligands (CInorganic chemistry · 2023Article
- Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification.Angewandte Chemie (International ed. in English) · 2023Article
- Mechanism of the Aryl-F Bond-Forming Step from Bi(V) Fluorides.Journal of the American Chemical Society · 2022Article
- Restoration of catalytic activity by the preservation of ligand structure: Cu-catalysed asymmetric conjugate addition with 1,1-diborylmethane.Chemical science · 2021Article
- Base-Assisted C-H Bond Cleavage in Cross-Coupling: Recent Insights into Mechanism, Speciation, and Cooperativity.Israel journal of chemistry · 2020Article
- Copper-Mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation.The Journal of organic chemistry · 2019Article
- Mechanochemistry allows carrying out sensitive organometallic reactions in air: glove-box-and-Schlenk-line-free synthesis of oxidative addition complexes from aryl halides and palladium(0).Chemical science · 2019Article
- Base-Promoted, Remote C-H Activation at a Cationic (ηJournal of the American Chemical Society · 2019Article
- Modular ipso/ ortho Difunctionalization of Aryl Bromides via Palladium/Norbornene Cooperative Catalysis.Journal of the American Chemical Society · 2018Article
- Palladium-Mediated Arylation of Lysine in Unprotected Peptides.Angewandte Chemie (International ed. in English) · 2017Article
- The Evolution of PdAccounts of chemical research · 2016Article
- A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides.Journal of the American Chemical Society · 2015Article
- In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides.Organometallics · 2015Article
- Palladium-Catalyzed Arylation of Fluoroalkylamines.Journal of the American Chemical Society · 2015Article
- Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling.Journal of the American Chemical Society · 2014Article
- Structure and Reactivity of [(L•Pd)Inorganica chimica acta · 2014Article
- PhenoFluor: Practical Synthesis, New Formulation, and Deoxyfluorination of Heteroaromatics.Organic process research & development · 2014Article
- Pd-catalyzed nucleophilic fluorination of aryl bromides.Journal of the American Chemical Society · 2014Article
- Mechanism of Electrophilic Fluorination with Pd(IV): Fluoride Capture and Subsequent Oxidative Fluoride TransferChemical science · 2014Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
Abstract
A mechanistic investigation of the Pd-catalyzed conversion of aryl triflates to fluorides is presented. Studies reveal that C-F reductive elimination from a LPd(II)(aryl)F complex (L = t-BuBrettPhos or RockPhos) does not occur when the aryl group is electron rich. Evidence is presented that a modified phosphine, generated in situ, serves as the actual supporting ligand during catalysis with such substrates. A preliminary study of the reactivity of a LPd(II)(aryl)F complex based on this modified ligand is reported.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.