ArticleJournal of the American Chemical Society2011
Molecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction.
Article in Journal of the American Chemical Society, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Formal Diels-Alder reaction of saturated carboxylic acids via C-H activation.Nature chemistry · 2026Article
- Palladium catalyzed ortho-C(spNature communications · 2024Article
- Dehydrogenative synthesis ofScience advances · 2024Article
- Regio-controllable [2+2] benzannulation with two adjacent C(spScience (New York, N.Y.) · 2023Article
- Iron-Catalyzed Cross-Coupling of α-Allenyl Esters with Grignard Reagents for the Synthesis of 1,3-Dienes.Organic letters · 2023Article
- Multiple remote C(spChemical science · 2022Article
- (NHC)Pd(II) hydride-catalyzed dehydroaromatization by olefin chain-walking isomerization and transfer-dehydrogenation.Nature communications · 2022Article
- Photo-induced copper-catalyzed sequential 1,n-HAT enabling the formation of cyclobutanols.Nature communications · 2021Article
- Synthesis of (E,E)-Dienones and (E,E)-Dienals via Palladium-Catalyzed γ,δ-Dehydrogenation of Enones and Enals.iScience · 2019Article
- Copper-catalyzed dehydrogenative γ-C(spNature communications · 2019Article
- Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions.Nature communications · 2018Article
- Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0)-Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene.Angewandte Chemie (International ed. in English) · 2017Article
- Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition.Journal of the American Chemical Society · 2016Article
- Asymmetric Syntheses of the Flavonoid Diels-Alder Natural Products Sanggenons C and O.Journal of the American Chemical Society · 2016Article
- Palladium-catalyzed aerobic oxidative dehydrogenation of cyclohexenes to substituted arene derivatives.Journal of the American Chemical Society · 2015Article
- N-Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/Brønsted acid co-catalyzed allylic C-H oxidation.Journal of the American Chemical Society · 2014Article
- General allylic C-H alkylation with tertiary nucleophiles.Journal of the American Chemical Society · 2014Article
- A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs.Tetrahedron · 2013Article
- Biomimetic dehydrogenative Diels-Alder cycloadditions: total syntheses of brosimones A and B.Angewandte Chemie (International ed. in English) · 2013Article
- Oxidative Heck vinylation for the synthesis of complex dienes and polyenes.Journal of the American Chemical Society · 2013Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-sulfoxide-catalyzed dehydrogenative Diels-Alder reaction that converts simple terminal olefins into complex cycloadducts in a single operation.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.