ArticleThe journal of physical chemistry letters2011
A Surrogate for Debye-Waller Factors from Dynamic Stokes Shifts.
Article in The journal of physical chemistry letters, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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Who cites it
3 citing papers in PubMed.
- Thermal Gradient Mid- and Far-Infrared Spectroscopy as Tools for Characterization of Protein Carbohydrate Lyophilizates.Molecular pharmaceutics · 2017Article
- Stabilization of proteins in solid form.Advanced drug delivery reviews · 2015Review
- Generalized localization model of relaxation in glass-forming liquids.Soft matter · 2012Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
We show that the short-time behavior of time-resolved fluorescence Stokes shifts (TRSS) are similar to that of the intermediate scattering function obtained from neutron scattering at q near the peak in the static structure factor for glycerol. This allows us to extract a Debye-Waller (DW) factor analog from TRSS data at times as short as 1 ps in a relatively simple way. Using the time-domain relaxation data obtained by this method we show that DW factors evaluated at times ≥ 40 ps can be directly influenced by α relaxation and thus should be used with caution when evaluating relationships between fast and slow dynamics in glassforming systems.
Identifiers
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Registered trials
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