ArticleNature communications2011
Revealing the molecular structure of single-molecule junctions in different conductance states by fishing-mode tip-enhanced Raman spectroscopy.
Article in Nature communications, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 37 papers.
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Who cites it
37 citing papers in PubMed, 258 citations in OpenAlex.
- Active Plasmonic Surfaces via Electrically Driven Actuation of DNA-Tethered Nanoparticles.ACS nano · 2026Article
- Plasmonic nanoparticle sensors: current progress, challenges, and future prospects.Nanoscale horizons · 2024Review
- Impact of Surface Enhanced Raman Spectroscopy in Catalysis.ACS nano · 2024Review
- An Infrared Nanospectroscopy Technique for the Study of Electric-Field-Induced Molecular Dynamics.Nano letters · 2024Article
- Atomic-precision control of plasmon-induced single-molecule switching in a metal-semiconductor nanojunction.Nature communications · 2024Article
- Remote-Controllable Interfacial Electron Tunneling at Heterogeneous Molecular Junctions via Tip-Induced Optoelectrical Engineering.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- A High-Density Raman Photometry for Tracking and Quantifying of AchE Activity in The Brain of Freely Moving Animals with Network.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Intermolecular and Electrode-Molecule Bonding in a Single Dimer Junction of Naphthalenethiol as Revealed by Surface-Enhanced Raman Scattering Combined with Transport Measurements.Journal of the American Chemical Society · 2023Article
- Local cation-tuned reversible single-molecule switch in electric double layer.Nature communications · 2023Article
- Dimensional Design for Surface-Enhanced Raman Spectroscopy.ACS materials Au · 2022Review
- Single-Molecule Surface-Enhanced Raman Spectroscopy.Sensors (Basel, Switzerland) · 2022Review
- Charge Transfer-Mediated Dramatic Enhancement of Raman Scattering upon Molecular Point Contact Formation.Nano letters · 2022Article
- Light-Driven Charge Transport and Optical Sensing in Molecular Junctions.Nanomaterials (Basel, Switzerland) · 2022Review
- Article
- Visually constructing the chemical structure of a single molecule by scanning Raman picoscopy.National science review · 2019Article
- Identifying the molecular adsorption site of a single molecule junction through combined Raman and conductance studies.Chemical science · 2019Article
- Nanoscale chemical imaging using tip-enhanced Raman spectroscopy.Nature protocols · 2019Article
- Tip-Enhanced Raman Spectroscopy with High-Order Fiber Vector Beam Excitation.Sensors (Basel, Switzerland) · 2018Article
- Synthesis of Spiked Plasmonic Nanorods with an Interior Nanogap for Quantitative Surface-Enhanced Raman Scattering Analysis.ACS omega · 2018Article
- Electrical and SERS detection of disulfide-mediated dimerization in single-molecule benzene-1,4-dithiol junctions.Chemical science · 2018Article
Corrections and comments
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Authors and funding
12 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The conductance of single-molecule junctions may be governed by the structure of the molecule in the gap or by the way it bonds with the leads, and the information contained in a Raman spectrum is ideal for examining both. Here we demonstrate that molecule-to-surface bonding may be characterized during electron transport by 'fishing-mode' tip-enhanced Raman spectroscopy (FM-TERS). This technique allows mutually verifiable single-molecule conductance and Raman signals with single-molecule contributions to be acquired simultaneously at room temperature. Density functional theory calculations reveal that the most significant spectral change seen for a gold-4,4'-bipyridine-gold junction results from the deformation of the pyridine ring in contact with the drain electrode at high voltage, and these calculations suggest that a stronger bonding interaction between the molecule and the drain may account for the nonlinear dependence of conductance on bias voltage. FM-TERS will lead to a better understanding of electron-transport processes in molecular junctions.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.