ArticleJournal of the American Chemical Society2011
Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex.
Article in Journal of the American Chemical Society, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
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Who cites it
27 citing papers in PubMed, 116 citations in OpenAlex.
- First Evidence for Ozonido-TMC Complexes of Iron and Cobalt.Angewandte Chemie (International ed. in English) · 2026Article
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- Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds.Journal of the American Chemical Society · 2022Article
- Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere.Journal of the American Chemical Society · 2021Article
- ScJournal of the American Chemical Society · 2020Article
- Surfactant-Mediated Solubilization of Magnetically Separable Nanocatalysts for the Oxidation of Alcohols.ACS omega · 2019Article
- Facile Conversion of syn-[FeAngewandte Chemie (International ed. in English) · 2019Article
- HACS catalysis · 2018Article
- Cross-linking of dicyclotyrosine by the cytochrome P450 enzyme CYP121 fromThe Journal of biological chemistry · 2017Article
- Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2017Review
- Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions.Inorganic chemistry · 2016Article
- Nuclear Resonance Vibrational Spectroscopic Definition of Peroxy Intermediates in Nonheme Iron Sites.Journal of the American Chemical Society · 2016Article
- Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺.Journal of the American Chemical Society · 2015Article
- An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway.Journal of the American Chemical Society · 2015Article
- Applications of density functional theory to iron-containing molecules of bioinorganic interest.Frontiers in chemistry · 2014Review
- Mechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases.ACS catalysis · 2013Article
- A Mononuclear Nonheme Iron(III)-Peroxo Complex Binding Redox-Inactive Metal Ions.Chemical science · 2013Article
- Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate.Journal of the American Chemical Society · 2013Article
- Article
- Comparison of high-spin and low-spin nonheme Fe(III)-OOH complexes in O-O bond homolysis and H-atom abstraction reactivities.Journal of the American Chemical Society · 2013Article
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
Abstract
We have generated a high-spin Fe(III)-OOH complex supported by tetramethylcyclam via protonation of its conjugate base and characterized it in detail using various spectroscopic methods. This Fe(III)-OOH species can be converted quantitatively to an Fe(IV)═O complex via O-O bond cleavage; this is the first example of such a conversion. This conversion is promoted by two factors: the strong Fe(III)-OOH bond, which inhibits Fe-O bond lysis, and the addition of protons, which facilitates O-O bond cleavage. This example provides a synthetic precedent for how O-O bond cleavage of high-spin Fe(III)-peroxo intermediates of non-heme iron enzymes may be promoted.
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