ReviewNature chemistry2011
Crystalline molecular flasks.
Review in Nature chemistry, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 78 papers.
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Who cites it
78 citing papers in PubMed.
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- Structural Elucidation of Nucleophilic Compounds through Synergistic Coordination and Hydrogen Bonding in a Metal-Organic Framework.Journal of the American Chemical Society · 2025Article
- Sorting polymerization in a bichannel metal-organic framework.Nature communications · 2025Article
- Supramolecular coordination cages as crystalline sponges through a symmetry mismatch strategy.Nature chemistry · 2025Article
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- Bioinspired metal-organic frameworks for aqueous environment decontamination: from laboratory scale to real-world technologies.Chemical communications (Cambridge, England) · 2024Review
- Template and Solid-State-Assisted Assembly of an MJournal of the American Chemical Society · 2024Article
- Design of Multivariate Biological Metal-Organic Frameworks: Toward Mimicking Active Sites of Enzymes.Inorganic chemistry · 2024Article
- Enhancing the Photosensitivity of Hypocrellin A by Perylene Diimide Metallacage-Based Host-Guest Complexation for Photodynamic Therapy.Nano-micro letters · 2024Article
- Host-Guest Cocrystallization of Phenanthrene[2]arene Macrocycles Facilitating Structure Determination of Liquid Organic Molecules.Molecules (Basel, Switzerland) · 2024Article
- Nested non-covalent interactions expand the functions of supramolecular polymer networks.Nature communications · 2024Article
- Synthesis of a Tetrahedral Metal-Organic Supramolecular Cage with Dendritic Carbazole Arms.International journal of molecular sciences · 2022Article
- Computational modeling to assist in the discovery of supramolecular materials.Annals of the New York Academy of Sciences · 2022Review
- Article
- Direct Z-Scheme Heterojunction Catalysts Constructed by Graphitic-CNanomaterials (Basel, Switzerland) · 2022Article
- Structure and absolute configuration of liquid molecules based on adamantane derivative cocrystallization.RSC advances · 2022Article
- Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.Journal of the American Chemical Society · 2021Article
- Recent advances and perspectives on supramolecular radical cages.Chemical science · 2021Review
18 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A variety of host compounds have been used as molecular-scale reaction vessels, protecting guests from their environment or restricting the space available around them, thus favouring particular reactions. Such molecular 'flasks' can endow guest molecules with reactivities that differ from those in bulk solvents. Here, we extend this concept to crystalline molecular flasks, solid-state crystalline networks with pores within which pseudo-solution-state reactions can take place. As the guest molecules can spontaneously align along the walls and channels of the hosts, structural changes in the substrates can be directly observed by in situ X-ray crystallography during reaction. Recently, this has enabled observation of the molecular structures of transient intermediates and other labile species, in the form of sequential structural snapshots of the chemical transformation. Here, we describe the principles, development and applications of crystalline molecular flasks.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.