ArticleBeilstein journal of organic chemistry2011
Formation of macrocyclic lactones in the Paternò-Büchi dimerization reaction.
Article in Beilstein journal of organic chemistry, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Designing Molecular Solar Thermal Systems Based on the Paternò-Büchi Reaction Coupled to Enzymatic Energy Release.ChemSusChem · 2025Article
- Oxetane synthesis through the Paternò-Büchi reaction.Molecules (Basel, Switzerland) · 2013Review
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Authors and funding
4 authors.
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Abstract
Furan-2-ylmethyl 2-oxoacetates 1a,b, in which the furan ring and the carbonyl moiety were embedded intramolecularly, were synthesized from commercially available furan-2-ylmethanol and their photochemical reaction (hν > 290 nm) was investigated. Twelve-membered macrocyclic lactones 2a,b with C(i) symmetry including two oxetane-rings, which are the Paternò-Büchi dimerization products, were isolated in ca. 20% yield. The intramolecular cyclization products, such as 3-alkoxyoxetane and 2,7-dioxabicyclo[2.2.1]hept-5-ene derivatives, were not detected in the photolysate.
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