ArticleChemical science2011
Metallacycle-Mediated Cross-Coupling with Substituted and Electronically Unactivated Alkenes.
Article in Chemical science, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
17 citing papers in PubMed, 60 citations in OpenAlex.
- Recent Progress in Steroid Synthesis Triggered by the Emergence of New Catalytic Methods.European journal of organic chemistry · 2020Article
- Synthesis of Isomerically Pure (Journal of the American Chemical Society · 2019Article
- A Complementary Process to Pauson-Khand-Type Annulation Reactions for the Construction of Fully Substituted Cyclopentenones.Organic letters · 2019Article
- Modern applications of low-valent early transition metals in synthesis and catalysis.Nature reviews. Chemistry · 2019Article
- Synthetic nat- or ent-steroids in as few as five chemical steps from epichlorohydrin.Nature chemistry · 2018Article
- The Development of Alkoxide-Directed Metallacycle-Mediated Annulative Cross-Coupling Chemistry.Israel journal of chemistry · 2017Article
- Metallacycle-Mediated Cross-Coupling in Natural Product Synthesis.Tetrahedron · 2016Article
- Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids.Journal of the American Chemical Society · 2016Article
- Cyclopropenes in Metallacycle-Mediated Cross-Coupling with Alkynes: Convergent Synthesis of Highly Substituted Vinylcyclopropanes.Organic letters · 2016Article
- Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium-Assisted Multicomponent Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2015Article
- LiOOTetrahedron letters · 2015Article
- Reaction design, discovery, and development as a foundation to function-oriented synthesis.Accounts of chemical research · 2015Article
- Stereochemical lability of azatitanacyclopropanes: dynamic kinetic resolution in reductive cross-coupling reactions with allylic alcohols.Chemical communications (Cambridge, England) · 2013Article
- Synthesis of the C1-C26 hexacyclic subunit of pectenotoxin 2.Organic letters · 2012Article
- Asymmetric synthesis of dihydroindanes by convergent alkoxide-directed metallacycle-mediated bond formation.Journal of the American Chemical Society · 2012Article
- Preparation of stereodefined homoallylic amines from the reductive cross-coupling of allylic alcohols with imines.The Journal of organic chemistry · 2010Article
- A Highly Chemo-, Regio-, and Stereoselective Metallacycle-Mediated Annulation Between a Conjugated Enyne and an Ene-Diyne.ARKIVOC : free online journal of organic chemistryArticle
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
This perspective surveys the history of- and recent advances in- metallacycle-mediated coupling chemistry of substituted alkenes. While the reaction of preformed metal-π complexes with ethylene was reported nearly 30 years ago, the generalization of this mode of bimolecular C-C bond formation to the regio- and stereoselective union of complex substrates has only recently begun to emerge. This perspective discusses early observations in this area, the challenges associated with controlling such processes, the evolution of a general strategy to overcome these challenges, and a summary of highly regio- and stereoselective convergent coupling reactions that are currently available by metallacycle-mediated cross-coupling with substituted alkenes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.