ArticleThe Journal of organic chemistry2011
Direct conversion of benzylic and allylic alcohols to phosphonates.
Article in The Journal of organic chemistry, 2011. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- High-Efficiency Light Emitters: 10-(Diphenylphosphoryl)-anthracenes from One-Pot Synthesis Including C-O-P to C-P(═O) Rearrangement.The Journal of organic chemistry · 2025Article
- Recent Advances in the Application of P(III)-Nucleophiles to Create New P-C Bonds through Michaelis-Arbuzov-Type Rearrangement.Topics in current chemistry (Cham) · 2024Review
- Total Synthesis of Loroxanthin.Marine drugs · 2022Article
- Improvements, Variations and Biomedical Applications of the Michaelis-Arbuzov Reaction.International journal of molecular sciences · 2022Review
- Synthesis of a Coumarin-Based Analogue of Schweinfurthin F.The Journal of organic chemistry · 2021Article
- Polymer-Supported Phosphoric, Phosphonic and Phosphinic Acids-From Synthesis to Properties and Applications in Separation Processes.Molecules (Basel, Switzerland) · 2020Review
- First DMAP-mediated direct conversion of Morita-Baylis-Hillman alcohols into γ-ketoallylphosphonates: Synthesis of γ-aminoallylphosphonates.Beilstein journal of organic chemistry · 2016Article
- Synthesis of α-Arylphosphonates Using Copper-Catalyzed α-Arylation and Deacylative α-Arylation of β-Ketophosphonates.Advanced synthesis & catalysis · 2011Article
- Synthesis and reactivity of alkyl-1,1,1-trisphosphonate esters.The Journal of organic chemistry · 2011Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Benzyl phosphonate esters often serve as reagents in Horner-Wadsworth-Emmons reactions. In most cases, they can be prepared from benzylic alcohols via formation of the corresponding halide followed by an Arbuzov reaction. To identify a more direct synthesis of phosphonate esters, we have developed a one-flask procedure for conversion of benzylic and allylic alcohols to the corresponding phosphonates through treatment with triethyl phosphite and ZnI(2).
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Registered trials
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