ReviewNature chemistry2009
The stabilization of fused-pentagon fullerene molecules.
Review in Nature chemistry, 2009. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Who cites it
25 citing papers in PubMed.
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- Correlated singular flat bands on the surface pentagonal lattice of ferromagnetic CoSNature communications · 2026Article
- An Electrochemical Dopamine Assay with Cobalt Oxide Palatinose Carbon Dots.Molecules (Basel, Switzerland) · 2025Article
- Hierarchical Supramolecular Aggregation of Molecular Nanoparticles for Granular Materials with Ultra High-Speed Impact-Resistance.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Kekulé Counts, Clar Numbers, and ZZ Polynomials for All Isomers of (5,6)-Fullerenes CMolecules (Basel, Switzerland) · 2024Article
- Recent advances in supramolecular fullerene chemistry.Chemical Society reviews · 2024Review
- Self-driven carbon atom implantation into fullerene embedding metal-carbon cluster.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Structural and Spectral Properties of a Nonclassical CACS omega · 2021Article
- Methods of hexagonal boron nitride exfoliation and its functionalization: covalent and non-covalent approaches.RSC advances · 2021Review
- Predicting the new carbon nanocages, fullerynes: a DFT study.Scientific reports · 2021Article
- Structural and spectral properties of a non-classical CRSC advances · 2021Article
- Structural Studies of Giant Empty and Endohedral Fullerenes.Frontiers in chemistry · 2020Review
- Article
- Transformation of doped graphite into cluster-encapsulated fullerene cages.Nature communications · 2017Article
- Eu@CMolecules (Basel, Switzerland) · 2017Article
- Mononuclear Clusterfullerene Single-Molecule Magnet Containing Strained Fused-Pentagons Stabilized by a Nearly Linear Metal Cyanide Cluster.Angewandte Chemie (International ed. in English) · 2017Article
- Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism.Journal of the American Chemical Society · 2016Article
- Penta-BxNy sheet: a density functional theory study of two-dimensional material.Scientific reports · 2016Article
- Sc3CH@C80: selective (13)C enrichment of the central carbon atom.Chemical communications (Cambridge, England) · 2016Article
- ScChemical science · 2016Article
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Authors and funding
4 authors.
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No grant is acknowledged in the PubMed record.
Abstract
The isolated pentagon rule (IPR) is now widely accepted as a general rule for determining the stability of all-carbon fullerene cages composed of hexagons and pentagons. Fullerenes that violate this rule have been deemed too reactive to be synthesized. The stabilization of non-IPR endohedral fullerenes depends on charge transfer from the encapsulated metal clusters (endoclusters) to fullerene cages, the electronic properties of empty all-carbon cages, the matching size and geometries of fullerene and endocluster, as well as the strong coordination of the metal ions to fused pentagons. The stability of non-IPR exohedral fullerenes can be rationalized primarily by both the 'strain-relief' and 'local-aromaticity' principles. This Review focuses on recent work on stabilization of non-IPR fullerenes, including theoretical and empirical principles, experimental methods, and molecular structures of fused-pentagon fullerenes characterized so far. The special chemical properties of non-IPR fullerenes that distinguish them from IPR-satisfying ones are also emphasized.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.