ArticleNature communications2010
Sequence-regulated vinyl copolymers by metal-catalysed step-growth radical polymerization.
Article in Nature communications, 2010. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
21 citing papers in PubMed, 239 citations in OpenAlex.
- Iterative Synthesis and Marine-Biodegradation Assessment of Discrete Oligomers Based on Poly(Butylene Succinate), Poly(Ethylene Terephthalate), Polyamide 6, and Polyisoprene.Macromolecules · 2025Article
- Sequence-Controlled Copolymerization of Structurally Well-Defined Multinuclear Zinc Acrylate Complexes and Styrene.Macromolecular rapid communications · 2025Article
- Controlled switching thiocarbonylthio end-groups enables interconvertible radical and cationic single-unit monomer insertions and RAFT polymerizations.Nature communications · 2024Article
- Recent Developments in Functional Polymers via the Kabachnik-Fields Reaction: The State of the Art.Molecules (Basel, Switzerland) · 2024Review
- Synthesis of thermo-responsive polymer gels composed of star-shaped block copolymers by copper-catalyzed living radical polymerization and click reaction.Science and technology of advanced materials · 2024Article
- In situ ligand-modulated activation of inert Ce(III/IV) into ozonation catalyst for efficient water treatment.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Spotting Trends in Organocatalyzed and Other Organomediated (De)polymerizations and Polymer Functionalizations.Angewandte Chemie (International ed. in English) · 2022Review
- Sidechain Metallopolymers with Precisely Controlled Structures: Synthesis and Application in Catalysis.Polymers · 2022Review
- Progress in the Preparation of Functional and (Bio)Degradable Polymers via Living Polymerizations.International journal of molecular sciences · 2020Review
- Synthesis of Poly(Polymers · 2019Article
- Self-regulation in chemical and bio-engineering materials for intelligent systems.CAAI Transactions on Intelligence Technology · 2018Article
- Fluorinated polymer surfactants bearing an alternating peptide skeleton prepared by three-component polycondensation.RSC advances · 2018Article
- Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels.Nature communications · 2018Article
- Sequence-controlled supramolecular terpolymerization directed by specific molecular recognitions.Nature communications · 2017Article
- A strategy for sequence control in vinyl polymers via iterative controlled radical cyclization.Nature communications · 2016Article
- Iterative exponential growth of stereo- and sequence-controlled polymers.Nature chemistry · 2015Article
- Degradable vinyl polymers for biomedical applications.Nature chemistry · 2015Review
- Synthesis of sequence-defined acrylate oligomersChemical science · 2015Article
- Sequentially hetero-functional, topological polymers by step-growth thiol-yne approach.Scientific reports · 2014Article
- Single-chain technology using discrete synthetic macromolecules.Nature chemistry · 2011Article
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Proteins and nucleic acids are sequence-regulated macromolecules with various properties originating from their perfectly sequenced primary structures. However, the sequence regulation of synthetic polymers, particularly vinyl polymers, has not been achieved and is one of the ultimate goals in polymer chemistry. In this study, we report a strategy to obtain sequence-regulated vinyl copolymers consisting of styrene, acrylate and vinyl chloride units using metal-catalysed step-growth radical polyaddition of designed monomers prepared from common vinyl monomer building blocks. Unprecedented ABCC-sequence-regulated copolymers with perfect vinyl chloride-styrene-acrylate-acrylate sequences were obtained by copper-catalysed step-growth radical polymerization of designed monomers possessing unconjugated C=C and reactive C-Cl bonds. This strategy may open a new route in the study of sequence-regulated synthetic polymers.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.